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(Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))zinc(II) 3.5-hydrate
The asymmetric unit of the title compound, (C(3)H(12)N(2))[Zn(C(7)H(3)NO(5))(2)]·3.5H(2)O, contains two formula units. The compound consists of an anionic complex, a doubly protonated propane-1,3-diamine as a counter-ion and 3.5 uncoordinated water molecules. The coordination polyhedron around the...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971239/ https://www.ncbi.nlm.nih.gov/pubmed/21578125 http://dx.doi.org/10.1107/S1600536809041634 |
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| author | Ghadermazi, Mohammad Manteghi, Faranak Aghabozorg, Hossein |
| author_facet | Ghadermazi, Mohammad Manteghi, Faranak Aghabozorg, Hossein |
| author_sort | Ghadermazi, Mohammad |
| collection | PubMed |
| description | The asymmetric unit of the title compound, (C(3)H(12)N(2))[Zn(C(7)H(3)NO(5))(2)]·3.5H(2)O, contains two formula units. The compound consists of an anionic complex, a doubly protonated propane-1,3-diamine as a counter-ion and 3.5 uncoordinated water molecules. The coordination polyhedron around the Zn(II )atom is distorted octahedral, defined by four O atoms and two N atoms from two Hchel (H(3)chel = 4-hydroxypyridine-2,6-dicarboxylic acid) ligands. In the crystal structure, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds along with π–π stacking interactions [centroid–centroid distance = 3.473 (2) Å] are observed to reinforce the crystal cohesion. |
| format | Text |
| id | pubmed-2971239 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712392010-12-30 (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))zinc(II) 3.5-hydrate Ghadermazi, Mohammad Manteghi, Faranak Aghabozorg, Hossein Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(3)H(12)N(2))[Zn(C(7)H(3)NO(5))(2)]·3.5H(2)O, contains two formula units. The compound consists of an anionic complex, a doubly protonated propane-1,3-diamine as a counter-ion and 3.5 uncoordinated water molecules. The coordination polyhedron around the Zn(II )atom is distorted octahedral, defined by four O atoms and two N atoms from two Hchel (H(3)chel = 4-hydroxypyridine-2,6-dicarboxylic acid) ligands. In the crystal structure, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds along with π–π stacking interactions [centroid–centroid distance = 3.473 (2) Å] are observed to reinforce the crystal cohesion. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971239/ /pubmed/21578125 http://dx.doi.org/10.1107/S1600536809041634 Text en © Ghadermazi et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ghadermazi, Mohammad Manteghi, Faranak Aghabozorg, Hossein (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))zinc(II) 3.5-hydrate |
| title | (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))zinc(II) 3.5-hydrate |
| title_full | (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))zinc(II) 3.5-hydrate |
| title_fullStr | (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))zinc(II) 3.5-hydrate |
| title_full_unstemmed | (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))zinc(II) 3.5-hydrate |
| title_short | (Propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))zinc(II) 3.5-hydrate |
| title_sort | (propane-1,3-diammonium) bis(4-hydroxypyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))zinc(ii) 3.5-hydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971239/ https://www.ncbi.nlm.nih.gov/pubmed/21578125 http://dx.doi.org/10.1107/S1600536809041634 |
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