catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]

In the title polymeric coordination compound, [Sn(C(6)H(5))(3)(C(9)H(8)N(3)O(3))](n), the Sn(IV) atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2...

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Detalles Bibliográficos
Autores principales: Cui, Jichun, Qiao, Yanling, Ding, Longhua, Yin, Handong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971240/
https://www.ncbi.nlm.nih.gov/pubmed/21578076
http://dx.doi.org/10.1107/S1600536809039981
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author Cui, Jichun
Qiao, Yanling
Ding, Longhua
Yin, Handong
author_facet Cui, Jichun
Qiao, Yanling
Ding, Longhua
Yin, Handong
author_sort Cui, Jichun
collection PubMed
description In the title polymeric coordination compound, [Sn(C(6)H(5))(3)(C(9)H(8)N(3)O(3))](n), the Sn(IV) atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2-(2-picolinoylhydrazono)propanoate ligand through one carbonyl O atom and one carboxyl­ate O atom, forming a chain structure propagating parallel to [100]. An intra­molecular N—H⋯O hydrogen bond is observed.
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spelling pubmed-29712402010-12-30 catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)] Cui, Jichun Qiao, Yanling Ding, Longhua Yin, Handong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric coordination compound, [Sn(C(6)H(5))(3)(C(9)H(8)N(3)O(3))](n), the Sn(IV) atom is in a distorted trigonal-bipyramidal geometry, being coordinated by two O atoms from two 2-(2-picolinoylhydrazono)propanoate ligands and three phenyl groups. Adjacent Sn atoms are bridged by the 2-(2-picolinoylhydrazono)propanoate ligand through one carbonyl O atom and one carboxyl­ate O atom, forming a chain structure propagating parallel to [100]. An intra­molecular N—H⋯O hydrogen bond is observed. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971240/ /pubmed/21578076 http://dx.doi.org/10.1107/S1600536809039981 Text en © Cui et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Jichun
Qiao, Yanling
Ding, Longhua
Yin, Handong
catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title_full catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title_fullStr catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title_full_unstemmed catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title_short catena-Poly[[triphenyl­tin(IV)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) O (1):O (2)]
title_sort catena-poly[[triphenyl­tin(iv)]-μ-2-(2-picolinoylhydrazono)propanoato-κ(2) o (1):o (2)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971240/
https://www.ncbi.nlm.nih.gov/pubmed/21578076
http://dx.doi.org/10.1107/S1600536809039981
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