Cargando…
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide
In the title compound, C(28)H(22)N(4)O(4), the molecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intramolecular N—H⋯(N,O) and...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971241/ https://www.ncbi.nlm.nih.gov/pubmed/21578434 http://dx.doi.org/10.1107/S1600536809041312 |
_version_ | 1782190579878199296 |
---|---|
author | Wang, Jing-Lin |
author_facet | Wang, Jing-Lin |
author_sort | Wang, Jing-Lin |
collection | PubMed |
description | In the title compound, C(28)H(22)N(4)O(4), the molecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intramolecular N—H⋯(N,O) and C—H⋯O hydrogen bonds contribute to the formation of the roughly planar configuration. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds, and weak π–π interactions between the pyridine rings and central benzene rings of the neighboring molecules [centroid–centroid separation = 3.9009 (6) Å]. |
format | Text |
id | pubmed-2971241 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712412010-12-30 N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide Wang, Jing-Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(22)N(4)O(4), the molecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intramolecular N—H⋯(N,O) and C—H⋯O hydrogen bonds contribute to the formation of the roughly planar configuration. The crystal packing is stabilized by intermolecular C—H⋯O hydrogen bonds, and weak π–π interactions between the pyridine rings and central benzene rings of the neighboring molecules [centroid–centroid separation = 3.9009 (6) Å]. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971241/ /pubmed/21578434 http://dx.doi.org/10.1107/S1600536809041312 Text en © Jing-Lin Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Wang, Jing-Lin N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title |
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title_full |
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title_fullStr |
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title_full_unstemmed |
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title_short |
N,N′-Di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
title_sort | n,n′-di-8-quinolyl-2,2′-(o-phenylenedioxy)diacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971241/ https://www.ncbi.nlm.nih.gov/pubmed/21578434 http://dx.doi.org/10.1107/S1600536809041312 |
work_keys_str_mv | AT wangjinglin nndi8quinolyl22ophenylenedioxydiacetamide |