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N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide

In the title compound, C(28)H(22)N(4)O(4), the mol­ecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intra­molecular N—H⋯(N,O) and...

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Detalles Bibliográficos
Autor principal: Wang, Jing-Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971241/
https://www.ncbi.nlm.nih.gov/pubmed/21578434
http://dx.doi.org/10.1107/S1600536809041312
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author Wang, Jing-Lin
author_facet Wang, Jing-Lin
author_sort Wang, Jing-Lin
collection PubMed
description In the title compound, C(28)H(22)N(4)O(4), the mol­ecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intra­molecular N—H⋯(N,O) and C—H⋯O hydrogen bonds contribute to the formation of the roughly planar configuration. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonds, and weak π–π inter­actions between the pyridine rings and central benzene rings of the neighboring mol­ecules [centroid–centroid separation = 3.9009 (6) Å].
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spelling pubmed-29712412010-12-30 N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide Wang, Jing-Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(22)N(4)O(4), the mol­ecule lies on a crystallographic twofold axis. The quinoline ring is essentially planar (give max or rms deviation 0.0186 Å), and the dihedral angle between the quinoline ring and the central benzene ring is 19.1 (4)°. Intra­molecular N—H⋯(N,O) and C—H⋯O hydrogen bonds contribute to the formation of the roughly planar configuration. The crystal packing is stabilized by inter­molecular C—H⋯O hydrogen bonds, and weak π–π inter­actions between the pyridine rings and central benzene rings of the neighboring mol­ecules [centroid–centroid separation = 3.9009 (6) Å]. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971241/ /pubmed/21578434 http://dx.doi.org/10.1107/S1600536809041312 Text en © Jing-Lin Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Jing-Lin
N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title_full N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title_fullStr N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title_full_unstemmed N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title_short N,N′-Di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
title_sort n,n′-di-8-quinolyl-2,2′-(o-phenyl­ene­di­oxy)diacetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971241/
https://www.ncbi.nlm.nih.gov/pubmed/21578434
http://dx.doi.org/10.1107/S1600536809041312
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