[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate

The metal atom in the title ylid–gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C—Au—C = 174.1 (2)°]. The mol­ecule has a short intra­molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol­ecules are linked by an Au⋯H(yl...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., Coetzee, Karolien, Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971244/
https://www.ncbi.nlm.nih.gov/pubmed/21578124
http://dx.doi.org/10.1107/S160053680904152X
Descripción
Sumario:The metal atom in the title ylid–gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C—Au—C = 174.1 (2)°]. The mol­ecule has a short intra­molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol­ecules are linked by an Au⋯H(ylid) inter­action (Au⋯H = 3.14 Å).

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