[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate

The metal atom in the title ylid–gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C—Au—C = 174.1 (2)°]. The mol­ecule has a short intra­molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol­ecules are linked by an Au⋯H(yl...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., Coetzee, Karolien, Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971244/
https://www.ncbi.nlm.nih.gov/pubmed/21578124
http://dx.doi.org/10.1107/S160053680904152X
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author Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Strasser, Christoph E.
collection PubMed
description The metal atom in the title ylid–gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C—Au—C = 174.1 (2)°]. The mol­ecule has a short intra­molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol­ecules are linked by an Au⋯H(ylid) inter­action (Au⋯H = 3.14 Å).
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spelling pubmed-29712442010-12-30 [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate Strasser, Christoph E. Coetzee, Karolien Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The metal atom in the title ylid–gold(I) adduct, [Au(C(6)F(5))(C(26)H(23)P)]·C(4)H(10)O, exists in a linear coordination environment [C—Au—C = 174.1 (2)°]. The mol­ecule has a short intra­molecular contact involving an aromatic H atom (Au⋯H = 2.64 Å); two adjacent mol­ecules are linked by an Au⋯H(ylid) inter­action (Au⋯H = 3.14 Å). International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971244/ /pubmed/21578124 http://dx.doi.org/10.1107/S160053680904152X Text en © Strasser et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Strasser, Christoph E.
Coetzee, Karolien
Cronje, Stephanie
Raubenheimer, Helgard G.
[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title_full [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title_fullStr [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title_full_unstemmed [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title_short [(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenyl­phospho­rane}(penta­fluoro­phenyl-κC)gold(I) diethyl ether solvate
title_sort [(3-methylphenyl)(triphenylphosphonio)methanide-κc]triphenyl­phospho­rane}(penta­fluoro­phenyl-κc)gold(i) diethyl ether solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971244/
https://www.ncbi.nlm.nih.gov/pubmed/21578124
http://dx.doi.org/10.1107/S160053680904152X
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AT cronjestephanie 3methylphenyltriphenylphosphoniomethanidekctriphenylphosphoranepentafluorophenylkcgoldidiethylethersolvate
AT raubenheimerhelgardg 3methylphenyltriphenylphosphoniomethanidekctriphenylphosphoranepentafluorophenylkcgoldidiethylethersolvate

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