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Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2) N (3):N (3′)] dihydrate]
In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxylate O atoms from two acetate ligands in a square-planar geometry. T...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971245/ https://www.ncbi.nlm.nih.gov/pubmed/21578204 http://dx.doi.org/10.1107/S160053680904464X |
Sumario: | In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxylate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. The Cu(II) atom lies on a center of inversion. |
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