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Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2) N (3):N (3′)] dihydrate]
In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxylate O atoms from two acetate ligands in a square-planar geometry. T...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971245/ https://www.ncbi.nlm.nih.gov/pubmed/21578204 http://dx.doi.org/10.1107/S160053680904464X |
| _version_ | 1782190581069381632 |
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| author | Deng, Yi-Fang Chen, Man-Sheng Kuang, Dai-Zhi Zhang, Chun-Hua |
| author_facet | Deng, Yi-Fang Chen, Man-Sheng Kuang, Dai-Zhi Zhang, Chun-Hua |
| author_sort | Deng, Yi-Fang |
| collection | PubMed |
| description | In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxylate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. The Cu(II) atom lies on a center of inversion. |
| format | Text |
| id | pubmed-2971245 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712452010-12-30 Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2) N (3):N (3′)] dihydrate] Deng, Yi-Fang Chen, Man-Sheng Kuang, Dai-Zhi Zhang, Chun-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title linear coordination polymer, {[Cu(C(2)H(3)O(2))(2)(C(12)H(10)N(4))]·2H(2)O}(n), the Cu(II) atom is coordinated by two N atoms from two different symmetry-related 1,4-diimidazol-1-ylbenzene (dib) ligands and two carboxylate O atoms from two acetate ligands in a square-planar geometry. The Cu atoms are linked by the dib ligands, forming an extended chain. These chains are linked by O—H⋯O hydrogen bonds into a three-dimensional supramolecular network. The Cu(II) atom lies on a center of inversion. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971245/ /pubmed/21578204 http://dx.doi.org/10.1107/S160053680904464X Text en © Deng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Deng, Yi-Fang Chen, Man-Sheng Kuang, Dai-Zhi Zhang, Chun-Hua Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2) N (3):N (3′)] dihydrate] |
| title | Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
N
(3):N
(3′)] dihydrate] |
| title_full | Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
N
(3):N
(3′)] dihydrate] |
| title_fullStr | Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
N
(3):N
(3′)] dihydrate] |
| title_full_unstemmed | Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
N
(3):N
(3′)] dihydrate] |
| title_short | Poly[[[bis(acetato-κO)copper(II)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
N
(3):N
(3′)] dihydrate] |
| title_sort | poly[[[bis(acetato-κo)copper(ii)]-μ-1,4-diimidazol-1-ylbenzene-κ(2)
n
(3):n
(3′)] dihydrate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971245/ https://www.ncbi.nlm.nih.gov/pubmed/21578204 http://dx.doi.org/10.1107/S160053680904464X |
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