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[(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I)
In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S—Au—P = 177.54 (3)°] can be traced to an intramolecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of molecules are stabilized by...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971249/ https://www.ncbi.nlm.nih.gov/pubmed/21578153 http://dx.doi.org/10.1107/S1600536809042767 |
| _version_ | 1782190581995274240 |
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| author | Ho, Soo Yei Tiekink, Edward R. T. |
| author_facet | Ho, Soo Yei Tiekink, Edward R. T. |
| author_sort | Ho, Soo Yei |
| collection | PubMed |
| description | In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S—Au—P = 177.54 (3)°] can be traced to an intramolecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of molecules are stabilized by a combination of C—H⋯O and C—H⋯π interactions. |
| format | Text |
| id | pubmed-2971249 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712492010-12-30 [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) Ho, Soo Yei Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Au(C(10)H(11)N(2)O(3)S)(C(18)H(33)P)], the gold(I) atom is linearly coordinated within a SP donor set. The distortion from linearity [S—Au—P = 177.54 (3)°] can be traced to an intramolecular Au⋯O contact of 3.009 (3) Å. In the crystal, layers of molecules are stabilized by a combination of C—H⋯O and C—H⋯π interactions. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971249/ /pubmed/21578153 http://dx.doi.org/10.1107/S1600536809042767 Text en © Ho and Tiekink 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ho, Soo Yei Tiekink, Edward R. T. [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title | [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title_full | [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title_fullStr | [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title_full_unstemmed | [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title_short | [(Z)-Isopropoxy(4-nitrophenylimino)methanethiolato-κS](tricyclohexylphosphine-κP)gold(I) |
| title_sort | [(z)-isopropoxy(4-nitrophenylimino)methanethiolato-κs](tricyclohexylphosphine-κp)gold(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971249/ https://www.ncbi.nlm.nih.gov/pubmed/21578153 http://dx.doi.org/10.1107/S1600536809042767 |
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