catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]

In the title compound, {[Mn(C(2)O(4))(C(8)H(7)N(3))]·1.5H(2)O}(n), the Mn(II) ion is chelated by two O,O′-bidentate oxalate ions and an N,N′-bidentate 3-(2-pyrid­yl)pyrazole mol­ecule, resulting in a distorted cis-MnN(2)O(4) octa­hedral geometry for the metal ion. The bridging oxalate ions generate...

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Detalles Bibliográficos
Autores principales: An, Zhe, Zhu, Ling
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971254/
https://www.ncbi.nlm.nih.gov/pubmed/21578202
http://dx.doi.org/10.1107/S1600536809044298
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author An, Zhe
Zhu, Ling
author_facet An, Zhe
Zhu, Ling
author_sort An, Zhe
collection PubMed
description In the title compound, {[Mn(C(2)O(4))(C(8)H(7)N(3))]·1.5H(2)O}(n), the Mn(II) ion is chelated by two O,O′-bidentate oxalate ions and an N,N′-bidentate 3-(2-pyrid­yl)pyrazole mol­ecule, resulting in a distorted cis-MnN(2)O(4) octa­hedral geometry for the metal ion. The bridging oxalate ions generate wave-like polymeric chains propagating in [001]. The packing is consolidated by N—H⋯O and O—H⋯O hydrogen bonds. One of the water O atoms lies on a crystallographic twofold axis.
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spelling pubmed-29712542010-12-30 catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate] An, Zhe Zhu, Ling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(2)O(4))(C(8)H(7)N(3))]·1.5H(2)O}(n), the Mn(II) ion is chelated by two O,O′-bidentate oxalate ions and an N,N′-bidentate 3-(2-pyrid­yl)pyrazole mol­ecule, resulting in a distorted cis-MnN(2)O(4) octa­hedral geometry for the metal ion. The bridging oxalate ions generate wave-like polymeric chains propagating in [001]. The packing is consolidated by N—H⋯O and O—H⋯O hydrogen bonds. One of the water O atoms lies on a crystallographic twofold axis. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971254/ /pubmed/21578202 http://dx.doi.org/10.1107/S1600536809044298 Text en © An and Zhu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
An, Zhe
Zhu, Ling
catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title_full catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title_fullStr catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title_full_unstemmed catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title_short catena-Poly[[[[3-(2-pyrid­yl)-1H-pyrazole]manganese(II)]-μ-oxalato] sesquihydrate]
title_sort catena-poly[[[[3-(2-pyrid­yl)-1h-pyrazole]manganese(ii)]-μ-oxalato] sesquihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971254/
https://www.ncbi.nlm.nih.gov/pubmed/21578202
http://dx.doi.org/10.1107/S1600536809044298
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