(3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one

In the title compound, C(26)H(23)NO, C—H⋯O hydrogen bonds generate a ribbon structure along the a axis. These ribbons further assemble into a one-dimensional sheet parallel to the ac plane via C—H⋯π inter­actions. The piperidin-4-one ring adopts a sofa conformation with the 1-benzyl group in the equ...

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Autores principales: Karthikeyan, N. S., Sathiyanarayanan, K., Aravindan, P. G., Rathore, R. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971257/
https://www.ncbi.nlm.nih.gov/pubmed/21578368
http://dx.doi.org/10.1107/S1600536809037659
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author Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Rathore, R. S.
author_facet Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Rathore, R. S.
author_sort Karthikeyan, N. S.
collection PubMed
description In the title compound, C(26)H(23)NO, C—H⋯O hydrogen bonds generate a ribbon structure along the a axis. These ribbons further assemble into a one-dimensional sheet parallel to the ac plane via C—H⋯π inter­actions. The piperidin-4-one ring adopts a sofa conformation with the 1-benzyl group in the equatorial position, and the 3- and 5-phenyl substituents stretched out on either side. The benzyl­idene units adopt E configurations and the 1-benzyl group is disposed towards the 3- substituent of the piperidin-4-one ring.
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spelling pubmed-29712572010-12-30 (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one Karthikeyan, N. S. Sathiyanarayanan, K. Aravindan, P. G. Rathore, R. S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(23)NO, C—H⋯O hydrogen bonds generate a ribbon structure along the a axis. These ribbons further assemble into a one-dimensional sheet parallel to the ac plane via C—H⋯π inter­actions. The piperidin-4-one ring adopts a sofa conformation with the 1-benzyl group in the equatorial position, and the 3- and 5-phenyl substituents stretched out on either side. The benzyl­idene units adopt E configurations and the 1-benzyl group is disposed towards the 3- substituent of the piperidin-4-one ring. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971257/ /pubmed/21578368 http://dx.doi.org/10.1107/S1600536809037659 Text en © Karthikeyan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Karthikeyan, N. S.
Sathiyanarayanan, K.
Aravindan, P. G.
Rathore, R. S.
(3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title_full (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title_fullStr (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title_full_unstemmed (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title_short (3E,5E)-1-Benzyl-3,5-dibenzyl­idenepiperidin-4-one
title_sort (3e,5e)-1-benzyl-3,5-dibenzyl­idenepiperidin-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971257/
https://www.ncbi.nlm.nih.gov/pubmed/21578368
http://dx.doi.org/10.1107/S1600536809037659
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