(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)

The complete mol­ecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a dist...

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Detalles Bibliográficos
Autores principales: Alizadeh, Robabeh, Kalateh, Khadijeh, Khoshtarkib, Zeinab, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971262/
https://www.ncbi.nlm.nih.gov/pubmed/21578171
http://dx.doi.org/10.1107/S1600536809043049
Descripción
Sumario:The complete mol­ecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a distorted ZnN(2)I(2) tetra­hedral geometry for the metal. In the crystal, there are weak π–π contacts between the pyridine rings [centroid–centroid distance = 3.978 (3) Å].

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