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(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)

The complete mol­ecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a dist...

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Autores principales: Alizadeh, Robabeh, Kalateh, Khadijeh, Khoshtarkib, Zeinab, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971262/
https://www.ncbi.nlm.nih.gov/pubmed/21578171
http://dx.doi.org/10.1107/S1600536809043049
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author Alizadeh, Robabeh
Kalateh, Khadijeh
Khoshtarkib, Zeinab
Ahmadi, Roya
Amani, Vahid
author_facet Alizadeh, Robabeh
Kalateh, Khadijeh
Khoshtarkib, Zeinab
Ahmadi, Roya
Amani, Vahid
author_sort Alizadeh, Robabeh
collection PubMed
description The complete mol­ecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a distorted ZnN(2)I(2) tetra­hedral geometry for the metal. In the crystal, there are weak π–π contacts between the pyridine rings [centroid–centroid distance = 3.978 (3) Å].
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spelling pubmed-29712622010-12-30 (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II) Alizadeh, Robabeh Kalateh, Khadijeh Khoshtarkib, Zeinab Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete mol­ecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a distorted ZnN(2)I(2) tetra­hedral geometry for the metal. In the crystal, there are weak π–π contacts between the pyridine rings [centroid–centroid distance = 3.978 (3) Å]. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971262/ /pubmed/21578171 http://dx.doi.org/10.1107/S1600536809043049 Text en © Alizadeh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Alizadeh, Robabeh
Kalateh, Khadijeh
Khoshtarkib, Zeinab
Ahmadi, Roya
Amani, Vahid
(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title_full (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title_fullStr (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title_full_unstemmed (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title_short (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
title_sort (6,6′-dimethyl-2,2′-bipyridine-κ(2) n,n′)diiodidozinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971262/
https://www.ncbi.nlm.nih.gov/pubmed/21578171
http://dx.doi.org/10.1107/S1600536809043049
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