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(6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II)
The complete molecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a dist...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971262/ https://www.ncbi.nlm.nih.gov/pubmed/21578171 http://dx.doi.org/10.1107/S1600536809043049 |
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author | Alizadeh, Robabeh Kalateh, Khadijeh Khoshtarkib, Zeinab Ahmadi, Roya Amani, Vahid |
author_facet | Alizadeh, Robabeh Kalateh, Khadijeh Khoshtarkib, Zeinab Ahmadi, Roya Amani, Vahid |
author_sort | Alizadeh, Robabeh |
collection | PubMed |
description | The complete molecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a distorted ZnN(2)I(2) tetrahedral geometry for the metal. In the crystal, there are weak π–π contacts between the pyridine rings [centroid–centroid distance = 3.978 (3) Å]. |
format | Text |
id | pubmed-2971262 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712622010-12-30 (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II) Alizadeh, Robabeh Kalateh, Khadijeh Khoshtarkib, Zeinab Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complete molecule of the title compound, [ZnI(2)(C(12)H(12)N(2))], is generated by crystallograpic twofold symmetry, with the Zn(II) atom lying on the rotation axis. The Zn(II) atom is coordinated by the N,N-bidentate 6,6′-dimethyl-2,2′-bipyridine ligand and two iodide ions, resulting in a distorted ZnN(2)I(2) tetrahedral geometry for the metal. In the crystal, there are weak π–π contacts between the pyridine rings [centroid–centroid distance = 3.978 (3) Å]. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971262/ /pubmed/21578171 http://dx.doi.org/10.1107/S1600536809043049 Text en © Alizadeh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Alizadeh, Robabeh Kalateh, Khadijeh Khoshtarkib, Zeinab Ahmadi, Roya Amani, Vahid (6,6′-Dimethyl-2,2′-bipyridine-κ(2) N,N′)diiodidozinc(II) |
title | (6,6′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)diiodidozinc(II) |
title_full | (6,6′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)diiodidozinc(II) |
title_fullStr | (6,6′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)diiodidozinc(II) |
title_full_unstemmed | (6,6′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)diiodidozinc(II) |
title_short | (6,6′-Dimethyl-2,2′-bipyridine-κ(2)
N,N′)diiodidozinc(II) |
title_sort | (6,6′-dimethyl-2,2′-bipyridine-κ(2)
n,n′)diiodidozinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971262/ https://www.ncbi.nlm.nih.gov/pubmed/21578171 http://dx.doi.org/10.1107/S1600536809043049 |
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