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(E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate

In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intra­molecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the mol­ecules are connected into a three-dimensi...

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Autores principales: Tong, Jun-Feng, Gao, Su-Xia, Dong, Wen-Kui, Li, Hong-Fu, Wu, Jian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971266/
https://www.ncbi.nlm.nih.gov/pubmed/21578358
http://dx.doi.org/10.1107/S1600536809042032
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author Tong, Jun-Feng
Gao, Su-Xia
Dong, Wen-Kui
Li, Hong-Fu
Wu, Jian-Chao
author_facet Tong, Jun-Feng
Gao, Su-Xia
Dong, Wen-Kui
Li, Hong-Fu
Wu, Jian-Chao
author_sort Tong, Jun-Feng
collection PubMed
description In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intra­molecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the mol­ecules are connected into a three-dimensional network via O—H⋯O and O—H⋯N inter­molecular hydrogen bonds, forming a centrosymmetric ring along the b axis with graph-set motif R (4) (4)(10). In addition, the short distances between the centroids of six-membered rings [3.555 (1) Å], indicate the existence of π–π stacking inter­actions, which may stabilize the crystal structure.
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spelling pubmed-29712662010-12-30 (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate Tong, Jun-Feng Gao, Su-Xia Dong, Wen-Kui Li, Hong-Fu Wu, Jian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intra­molecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the mol­ecules are connected into a three-dimensional network via O—H⋯O and O—H⋯N inter­molecular hydrogen bonds, forming a centrosymmetric ring along the b axis with graph-set motif R (4) (4)(10). In addition, the short distances between the centroids of six-membered rings [3.555 (1) Å], indicate the existence of π–π stacking inter­actions, which may stabilize the crystal structure. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971266/ /pubmed/21578358 http://dx.doi.org/10.1107/S1600536809042032 Text en © Tong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tong, Jun-Feng
Gao, Su-Xia
Dong, Wen-Kui
Li, Hong-Fu
Wu, Jian-Chao
(E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title_full (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title_fullStr (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title_full_unstemmed (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title_short (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
title_sort (e)-2-{4-[1-(hydroxyimino)ethyl]phenyl­iminomethyl}-6-methoxyphenol mono­hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971266/
https://www.ncbi.nlm.nih.gov/pubmed/21578358
http://dx.doi.org/10.1107/S1600536809042032
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