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(E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate
In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intramolecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the molecules are connected into a three-dimensi...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971266/ https://www.ncbi.nlm.nih.gov/pubmed/21578358 http://dx.doi.org/10.1107/S1600536809042032 |
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author | Tong, Jun-Feng Gao, Su-Xia Dong, Wen-Kui Li, Hong-Fu Wu, Jian-Chao |
author_facet | Tong, Jun-Feng Gao, Su-Xia Dong, Wen-Kui Li, Hong-Fu Wu, Jian-Chao |
author_sort | Tong, Jun-Feng |
collection | PubMed |
description | In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intramolecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the molecules are connected into a three-dimensional network via O—H⋯O and O—H⋯N intermolecular hydrogen bonds, forming a centrosymmetric ring along the b axis with graph-set motif R (4) (4)(10). In addition, the short distances between the centroids of six-membered rings [3.555 (1) Å], indicate the existence of π–π stacking interactions, which may stabilize the crystal structure. |
format | Text |
id | pubmed-2971266 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712662010-12-30 (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate Tong, Jun-Feng Gao, Su-Xia Dong, Wen-Kui Li, Hong-Fu Wu, Jian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)N(2)O(3)·H(2)O, the benzene rings are nearly coplanar with each other, forming a dihedral angle of 4.46 (3)°. There is a strong intramolecular O—H⋯N hydrogen bond which results in a six-membered ring. In the crystal, the molecules are connected into a three-dimensional network via O—H⋯O and O—H⋯N intermolecular hydrogen bonds, forming a centrosymmetric ring along the b axis with graph-set motif R (4) (4)(10). In addition, the short distances between the centroids of six-membered rings [3.555 (1) Å], indicate the existence of π–π stacking interactions, which may stabilize the crystal structure. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971266/ /pubmed/21578358 http://dx.doi.org/10.1107/S1600536809042032 Text en © Tong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Tong, Jun-Feng Gao, Su-Xia Dong, Wen-Kui Li, Hong-Fu Wu, Jian-Chao (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title | (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title_full | (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title_fullStr | (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title_full_unstemmed | (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title_short | (E)-2-{4-[1-(Hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
title_sort | (e)-2-{4-[1-(hydroxyimino)ethyl]phenyliminomethyl}-6-methoxyphenol monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971266/ https://www.ncbi.nlm.nih.gov/pubmed/21578358 http://dx.doi.org/10.1107/S1600536809042032 |
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