(E)-1-Nitro-4-(2-nitro­ethen­yl)benzene

The asymmetric unit of the title compound, C(8)H(6)N(2)O(4), consists of two independent mol­ecules with similar geometries, each adopting a trans configuration about the olefinic double bond. The two mol­ecules are both almost planar (r.m.s. deviations = 0.034 and 0.035 Å) and form a dihedral angle...

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Detalles Bibliográficos
Autor principal: Jing, Lin-Hai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971267/
https://www.ncbi.nlm.nih.gov/pubmed/21578401
http://dx.doi.org/10.1107/S1600536809042561
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author Jing, Lin-Hai
author_facet Jing, Lin-Hai
author_sort Jing, Lin-Hai
collection PubMed
description The asymmetric unit of the title compound, C(8)H(6)N(2)O(4), consists of two independent mol­ecules with similar geometries, each adopting a trans configuration about the olefinic double bond. The two mol­ecules are both almost planar (r.m.s. deviations = 0.034 and 0.035 Å) and form a dihedral angle of 83.62 (2)°. Short N⋯O contacts [2.834 (3)–2.861 (3) Å] are observed between the nitro groups of neighbouring mol­ecules, with the O atom located directly atop the p orbital of the N atom. In the crystal, the mol­ecules are linked into a three-dimensional network by the N⋯O inter­actions and by C—H⋯O hydrogen bonds.
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spelling pubmed-29712672010-12-30 (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene Jing, Lin-Hai Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(6)N(2)O(4), consists of two independent mol­ecules with similar geometries, each adopting a trans configuration about the olefinic double bond. The two mol­ecules are both almost planar (r.m.s. deviations = 0.034 and 0.035 Å) and form a dihedral angle of 83.62 (2)°. Short N⋯O contacts [2.834 (3)–2.861 (3) Å] are observed between the nitro groups of neighbouring mol­ecules, with the O atom located directly atop the p orbital of the N atom. In the crystal, the mol­ecules are linked into a three-dimensional network by the N⋯O inter­actions and by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971267/ /pubmed/21578401 http://dx.doi.org/10.1107/S1600536809042561 Text en © Lin-Hai Jing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jing, Lin-Hai
(E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title_full (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title_fullStr (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title_full_unstemmed (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title_short (E)-1-Nitro-4-(2-nitro­ethen­yl)benzene
title_sort (e)-1-nitro-4-(2-nitro­ethen­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971267/
https://www.ncbi.nlm.nih.gov/pubmed/21578401
http://dx.doi.org/10.1107/S1600536809042561
work_keys_str_mv AT jinglinhai e1nitro42nitroethenylbenzene

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