(2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate

In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa­hedral geometry. Chelation is isobidentate for one dithio­carbamate ligand and anisobidentate for the other. The chloroform solvent mol­ecule is disordered over two positions of...

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Detalles Bibliográficos
Autores principales: Baba, Ibrahim, Nik Intan, Nik Ismail, Yamin, Bohari M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971268/
https://www.ncbi.nlm.nih.gov/pubmed/21578118
http://dx.doi.org/10.1107/S1600536809041294
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author Baba, Ibrahim
Nik Intan, Nik Ismail
Yamin, Bohari M.
Ng, Seik Weng
author_facet Baba, Ibrahim
Nik Intan, Nik Ismail
Yamin, Bohari M.
Ng, Seik Weng
author_sort Baba, Ibrahim
collection PubMed
description In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa­hedral geometry. Chelation is isobidentate for one dithio­carbamate ligand and anisobidentate for the other. The chloroform solvent mol­ecule is disordered over two positions of equal occupancy.
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spelling pubmed-29712682010-12-30 (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate Baba, Ibrahim Nik Intan, Nik Ismail Yamin, Bohari M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(9)H(10)NS(2))(2)(C(10)H(8)N(2))]·CHCl(3), the Cd(II) atom exists in an all-cis distorted octa­hedral geometry. Chelation is isobidentate for one dithio­carbamate ligand and anisobidentate for the other. The chloroform solvent mol­ecule is disordered over two positions of equal occupancy. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971268/ /pubmed/21578118 http://dx.doi.org/10.1107/S1600536809041294 Text en © Baba et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Baba, Ibrahim
Nik Intan, Nik Ismail
Yamin, Bohari M.
Ng, Seik Weng
(2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title_full (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title_short (2,2′-Bipyridine-κ(2) N,N′)bis­(N-ethyl-N-phenyl­dithio­carbamato-κ(2) S,S′)cadmium(II) chloro­form solvate
title_sort (2,2′-bipyridine-κ(2) n,n′)bis­(n-ethyl-n-phenyl­dithio­carbamato-κ(2) s,s′)cadmium(ii) chloro­form solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971268/
https://www.ncbi.nlm.nih.gov/pubmed/21578118
http://dx.doi.org/10.1107/S1600536809041294
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