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Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I)
The title compound, (C(8)H(20)N)(2)[Cu(2)Mo(2)(C(2)H(4)S(2))(2)(CN)(2)S(4)], is a sulfide-bridged tetranuclear complex in which the complex anion comprises one [(edt)(2)Mo(2)S(2)(μ-S)(2)](2−) unit (edt = ethanedithiolate) and two CuCN units joined through six Cu—μ(3)-S bonds, thus forming a cubane-...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971270/ https://www.ncbi.nlm.nih.gov/pubmed/21578207 http://dx.doi.org/10.1107/S1600536809044821 |
| _version_ | 1782190586842841088 |
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| author | You, Xiu-Li Liu, Yue-Long |
| author_facet | You, Xiu-Li Liu, Yue-Long |
| author_sort | You, Xiu-Li |
| collection | PubMed |
| description | The title compound, (C(8)H(20)N)(2)[Cu(2)Mo(2)(C(2)H(4)S(2))(2)(CN)(2)S(4)], is a sulfide-bridged tetranuclear complex in which the complex anion comprises one [(edt)(2)Mo(2)S(2)(μ-S)(2)](2−) unit (edt = ethanedithiolate) and two CuCN units joined through six Cu—μ(3)-S bonds, thus forming a cubane-like [Mo(2)S(4)Cu(2)] core. There are two independent cation–anion complex entities in the asymmetric unit. Bond distances are normal for this type of complex [ranges: Mo—S = 2.193 (2)–2.390 (2); Cu—S = 2.266 (2)–2.470 (2); Cu—C = 1.899 (7)–1.911 (9) Å]. One of the thiolato C atoms is disordered over two sites in a 0.52 (3):0.48 (3) ratio. |
| format | Text |
| id | pubmed-2971270 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712702010-12-30 Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) You, Xiu-Li Liu, Yue-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(20)N)(2)[Cu(2)Mo(2)(C(2)H(4)S(2))(2)(CN)(2)S(4)], is a sulfide-bridged tetranuclear complex in which the complex anion comprises one [(edt)(2)Mo(2)S(2)(μ-S)(2)](2−) unit (edt = ethanedithiolate) and two CuCN units joined through six Cu—μ(3)-S bonds, thus forming a cubane-like [Mo(2)S(4)Cu(2)] core. There are two independent cation–anion complex entities in the asymmetric unit. Bond distances are normal for this type of complex [ranges: Mo—S = 2.193 (2)–2.390 (2); Cu—S = 2.266 (2)–2.470 (2); Cu—C = 1.899 (7)–1.911 (9) Å]. One of the thiolato C atoms is disordered over two sites in a 0.52 (3):0.48 (3) ratio. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971270/ /pubmed/21578207 http://dx.doi.org/10.1107/S1600536809044821 Text en © You and Liu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers You, Xiu-Li Liu, Yue-Long Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title | Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title_full | Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title_fullStr | Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title_full_unstemmed | Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title_short | Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(V)dicopper(I) |
| title_sort | tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ(3)-sulfido-dimolybdenum(v)dicopper(i) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971270/ https://www.ncbi.nlm.nih.gov/pubmed/21578207 http://dx.doi.org/10.1107/S1600536809044821 |
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