catena-Poly[[sodium-di-μ-β-d-glucose] chloride]

The asymmetric unit of the title compound, {[Na(C(6)H(12)O(6))(2)]Cl}(n), contains six glucose mol­ecules, three Na(+) ions and three Cl(−) ions, i.e. three independent {[Na(C(6)H(12)O(6))(2)]Cl} units. Each of these units forms polymeric chains along the c axis. Each Na(+) ion is surrounded by six...

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Detalles Bibliográficos
Autores principales: Wong, K. C., Hamid, Abdul, Baharuddin, S., Quah, Ching Kheng, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971272/
https://www.ncbi.nlm.nih.gov/pubmed/21578072
http://dx.doi.org/10.1107/S1600536809039993
Descripción
Sumario:The asymmetric unit of the title compound, {[Na(C(6)H(12)O(6))(2)]Cl}(n), contains six glucose mol­ecules, three Na(+) ions and three Cl(−) ions, i.e. three independent {[Na(C(6)H(12)O(6))(2)]Cl} units. Each of these units forms polymeric chains along the c axis. Each Na(+) ion is surrounded by six O atoms from four glucose mol­ecules, forming a distorted octa­hedral geometry. All glucose mol­ecules adopt chair conformations. The constituent units are linked into a three-dimensional framework by O—H⋯Cl and O—H⋯O hydrogen bonds, utilizing all the O—H groups.

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