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2-Bromo-3-nitrobenzaldehyde
The title compound, C(7)H(4)BrNO(3), was isolated as a by-product while attempting to prepare a diselenide. There is a close intramolecular Br⋯O contact [2.984 (2) Å]. The molecules form loosely associated dimers held together by weak intermolecular Br⋯O interactions with the nitro O atoms [Br⋯O...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971273/ https://www.ncbi.nlm.nih.gov/pubmed/21578355 http://dx.doi.org/10.1107/S160053680904104X |
| _version_ | 1782190587621933056 |
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| author | Singh, Vijay P. Singh, Harkesh B. Butcher, Ray J. |
| author_facet | Singh, Vijay P. Singh, Harkesh B. Butcher, Ray J. |
| author_sort | Singh, Vijay P. |
| collection | PubMed |
| description | The title compound, C(7)H(4)BrNO(3), was isolated as a by-product while attempting to prepare a diselenide. There is a close intramolecular Br⋯O contact [2.984 (2) Å]. The molecules form loosely associated dimers held together by weak intermolecular Br⋯O interactions with the nitro O atoms [Br⋯O = 3.179 (3) Å]. As a result of these interactions, there is also a close Br⋯Br intermolecular contact [3.8714 (6) Å]. In addition, there are weak intermolecular C—H⋯O interactions. The combination of these interactions produces sheets which propagate in the (210) and ([Image: see text]10) directions perpendicular to c. |
| format | Text |
| id | pubmed-2971273 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712732010-12-30 2-Bromo-3-nitrobenzaldehyde Singh, Vijay P. Singh, Harkesh B. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(4)BrNO(3), was isolated as a by-product while attempting to prepare a diselenide. There is a close intramolecular Br⋯O contact [2.984 (2) Å]. The molecules form loosely associated dimers held together by weak intermolecular Br⋯O interactions with the nitro O atoms [Br⋯O = 3.179 (3) Å]. As a result of these interactions, there is also a close Br⋯Br intermolecular contact [3.8714 (6) Å]. In addition, there are weak intermolecular C—H⋯O interactions. The combination of these interactions produces sheets which propagate in the (210) and ([Image: see text]10) directions perpendicular to c. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971273/ /pubmed/21578355 http://dx.doi.org/10.1107/S160053680904104X Text en © Singh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Singh, Vijay P. Singh, Harkesh B. Butcher, Ray J. 2-Bromo-3-nitrobenzaldehyde |
| title | 2-Bromo-3-nitrobenzaldehyde |
| title_full | 2-Bromo-3-nitrobenzaldehyde |
| title_fullStr | 2-Bromo-3-nitrobenzaldehyde |
| title_full_unstemmed | 2-Bromo-3-nitrobenzaldehyde |
| title_short | 2-Bromo-3-nitrobenzaldehyde |
| title_sort | 2-bromo-3-nitrobenzaldehyde |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971273/ https://www.ncbi.nlm.nih.gov/pubmed/21578355 http://dx.doi.org/10.1107/S160053680904104X |
| work_keys_str_mv | AT singhvijayp 2bromo3nitrobenzaldehyde AT singhharkeshb 2bromo3nitrobenzaldehyde AT butcherrayj 2bromo3nitrobenzaldehyde |