Bis[(18-crown-6-κ(6) O)sodium] (18-crown-6-1κ(6) O)-μ-thiocyanato-1:2κ(2) S:N-pentathio­cyanato-2κ(5) N-indate(III)sodium 1,2-dichloro­ethane sesquisolvate

The title complex, [Na(C(12)H(24)O(6))](2)[InNa(NCS)(6)(C(12)H(24)O(6))]·1.5C(2)H(4)Cl(2), has been synthesized by the reaction of 18-crown-6 with InCl(3) and NaSCN. The In atom has a six-coordinate octa­hedral environment, being bonded to the N atoms of six thio­cyanate groups. The bond lengths and...

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Detalles Bibliográficos
Autor principal: Kong, Lingqian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971278/
https://www.ncbi.nlm.nih.gov/pubmed/21578075
http://dx.doi.org/10.1107/S1600536809039282
Descripción
Sumario:The title complex, [Na(C(12)H(24)O(6))](2)[InNa(NCS)(6)(C(12)H(24)O(6))]·1.5C(2)H(4)Cl(2), has been synthesized by the reaction of 18-crown-6 with InCl(3) and NaSCN. The In atom has a six-coordinate octa­hedral environment, being bonded to the N atoms of six thio­cyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short inter­molecular contacts.

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