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Bis[(18-crown-6-κ(6) O)sodium] (18-crown-6-1κ(6) O)-μ-thiocyanato-1:2κ(2) S:N-pentathiocyanato-2κ(5) N-indate(III)sodium 1,2-dichloroethane sesquisolvate
The title complex, [Na(C(12)H(24)O(6))](2)[InNa(NCS)(6)(C(12)H(24)O(6))]·1.5C(2)H(4)Cl(2), has been synthesized by the reaction of 18-crown-6 with InCl(3) and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971278/ https://www.ncbi.nlm.nih.gov/pubmed/21578075 http://dx.doi.org/10.1107/S1600536809039282 |
| _version_ | 1782190588802629632 |
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| author | Kong, Lingqian |
| author_facet | Kong, Lingqian |
| author_sort | Kong, Lingqian |
| collection | PubMed |
| description | The title complex, [Na(C(12)H(24)O(6))](2)[InNa(NCS)(6)(C(12)H(24)O(6))]·1.5C(2)H(4)Cl(2), has been synthesized by the reaction of 18-crown-6 with InCl(3) and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short intermolecular contacts. |
| format | Text |
| id | pubmed-2971278 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29712782010-12-30 Bis[(18-crown-6-κ(6) O)sodium] (18-crown-6-1κ(6) O)-μ-thiocyanato-1:2κ(2) S:N-pentathiocyanato-2κ(5) N-indate(III)sodium 1,2-dichloroethane sesquisolvate Kong, Lingqian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Na(C(12)H(24)O(6))](2)[InNa(NCS)(6)(C(12)H(24)O(6))]·1.5C(2)H(4)Cl(2), has been synthesized by the reaction of 18-crown-6 with InCl(3) and NaSCN. The In atom has a six-coordinate octahedral environment, being bonded to the N atoms of six thiocyanate groups. The bond lengths and angles show normal values. The crystal packing exhibits no significantly short intermolecular contacts. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971278/ /pubmed/21578075 http://dx.doi.org/10.1107/S1600536809039282 Text en © Lingqian Kong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kong, Lingqian Bis[(18-crown-6-κ(6) O)sodium] (18-crown-6-1κ(6) O)-μ-thiocyanato-1:2κ(2) S:N-pentathiocyanato-2κ(5) N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title | Bis[(18-crown-6-κ(6)
O)sodium] (18-crown-6-1κ(6)
O)-μ-thiocyanato-1:2κ(2)
S:N-pentathiocyanato-2κ(5)
N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_full | Bis[(18-crown-6-κ(6)
O)sodium] (18-crown-6-1κ(6)
O)-μ-thiocyanato-1:2κ(2)
S:N-pentathiocyanato-2κ(5)
N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_fullStr | Bis[(18-crown-6-κ(6)
O)sodium] (18-crown-6-1κ(6)
O)-μ-thiocyanato-1:2κ(2)
S:N-pentathiocyanato-2κ(5)
N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_full_unstemmed | Bis[(18-crown-6-κ(6)
O)sodium] (18-crown-6-1κ(6)
O)-μ-thiocyanato-1:2κ(2)
S:N-pentathiocyanato-2κ(5)
N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_short | Bis[(18-crown-6-κ(6)
O)sodium] (18-crown-6-1κ(6)
O)-μ-thiocyanato-1:2κ(2)
S:N-pentathiocyanato-2κ(5)
N-indate(III)sodium 1,2-dichloroethane sesquisolvate |
| title_sort | bis[(18-crown-6-κ(6)
o)sodium] (18-crown-6-1κ(6)
o)-μ-thiocyanato-1:2κ(2)
s:n-pentathiocyanato-2κ(5)
n-indate(iii)sodium 1,2-dichloroethane sesquisolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971278/ https://www.ncbi.nlm.nih.gov/pubmed/21578075 http://dx.doi.org/10.1107/S1600536809039282 |
| work_keys_str_mv | AT konglingqian bis18crown6k6osodium18crown61k6omthiocyanato12k2snpentathiocyanato2k5nindateiiisodium12dichloroethanesesquisolvate |