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Aqua(2-hydroxy-5-sulfonatobenzoato-κO (1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO(2)N(4) oc...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/ https://www.ncbi.nlm.nih.gov/pubmed/21578053 http://dx.doi.org/10.1107/S1600536809039154 |
Sumario: | In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO(2)N(4) octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. |
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