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Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)

In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water mol­ecule. This results in a distorted cis-ZnO(2)N(4) oc...

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Detalles Bibliográficos
Autores principales: Han, Qiang, Wang, Xiang-Cheng, Li, Xiu-Ying, Yao, Guan-Xin, Yan, Yong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/
https://www.ncbi.nlm.nih.gov/pubmed/21578053
http://dx.doi.org/10.1107/S1600536809039154
Descripción
Sumario:In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water mol­ecule. This results in a distorted cis-ZnO(2)N(4) octa­hedral coordination geometry for the metal ion. In the crystal, mol­ecules are expanded into a three-dimensional supra­molecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking inter­actions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].