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Aqua(2-hydroxy-5-sulfonatobenzoato-κO (1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO(2)N(4) oc...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/ https://www.ncbi.nlm.nih.gov/pubmed/21578053 http://dx.doi.org/10.1107/S1600536809039154 |
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author | Han, Qiang Wang, Xiang-Cheng Li, Xiu-Ying Yao, Guan-Xin Yan, Yong-Sheng |
author_facet | Han, Qiang Wang, Xiang-Cheng Li, Xiu-Ying Yao, Guan-Xin Yan, Yong-Sheng |
author_sort | Han, Qiang |
collection | PubMed |
description | In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO(2)N(4) octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. |
format | Text |
id | pubmed-2971279 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712792010-12-30 Aqua(2-hydroxy-5-sulfonatobenzoato-κO (1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))zinc(II) Han, Qiang Wang, Xiang-Cheng Li, Xiu-Ying Yao, Guan-Xin Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water molecule. This results in a distorted cis-ZnO(2)N(4) octahedral coordination geometry for the metal ion. In the crystal, molecules are expanded into a three-dimensional supramolecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking interactions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971279/ /pubmed/21578053 http://dx.doi.org/10.1107/S1600536809039154 Text en © Han et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Han, Qiang Wang, Xiang-Cheng Li, Xiu-Ying Yao, Guan-Xin Yan, Yong-Sheng Aqua(2-hydroxy-5-sulfonatobenzoato-κO (1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2) N (7),N (8))zinc(II) |
title | Aqua(2-hydroxy-5-sulfonatobenzoato-κO
(1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))zinc(II) |
title_full | Aqua(2-hydroxy-5-sulfonatobenzoato-κO
(1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))zinc(II) |
title_fullStr | Aqua(2-hydroxy-5-sulfonatobenzoato-κO
(1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))zinc(II) |
title_full_unstemmed | Aqua(2-hydroxy-5-sulfonatobenzoato-κO
(1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))zinc(II) |
title_short | Aqua(2-hydroxy-5-sulfonatobenzoato-κO
(1))bis(2-phenyl-1H-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
N
(7),N
(8))zinc(II) |
title_sort | aqua(2-hydroxy-5-sulfonatobenzoato-κo
(1))bis(2-phenyl-1h-1,3,7,8-tetraazacyclopenta[l]phenanthrene-κ(2)
n
(7),n
(8))zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/ https://www.ncbi.nlm.nih.gov/pubmed/21578053 http://dx.doi.org/10.1107/S1600536809039154 |
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