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Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)

In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water mol­ecule. This results in a distorted cis-ZnO(2)N(4) oc...

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Detalles Bibliográficos
Autores principales: Han, Qiang, Wang, Xiang-Cheng, Li, Xiu-Ying, Yao, Guan-Xin, Yan, Yong-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/
https://www.ncbi.nlm.nih.gov/pubmed/21578053
http://dx.doi.org/10.1107/S1600536809039154
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author Han, Qiang
Wang, Xiang-Cheng
Li, Xiu-Ying
Yao, Guan-Xin
Yan, Yong-Sheng
author_facet Han, Qiang
Wang, Xiang-Cheng
Li, Xiu-Ying
Yao, Guan-Xin
Yan, Yong-Sheng
author_sort Han, Qiang
collection PubMed
description In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water mol­ecule. This results in a distorted cis-ZnO(2)N(4) octa­hedral coordination geometry for the metal ion. In the crystal, mol­ecules are expanded into a three-dimensional supra­molecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking inter­actions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å].
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spelling pubmed-29712792010-12-30 Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II) Han, Qiang Wang, Xiang-Cheng Li, Xiu-Ying Yao, Guan-Xin Yan, Yong-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(7)H(4)O(6)S)(C(19)H(12)N(4))(2)(H(2)O)], the Zn(II) ion is coordinated by two N,N′-bidentate 2-phenyl-1H-1,3,7,8-tetra­azacyclo­penta­[l]phenanthrene ligands, one O-monodentate 5-sulfosalicylate dianion and a water mol­ecule. This results in a distorted cis-ZnO(2)N(4) octa­hedral coordination geometry for the metal ion. In the crystal, mol­ecules are expanded into a three-dimensional supra­molecular motif via O—H⋯O, O—H⋯N and N—H⋯(O,S) hydrogen bonds. In addition, π–π stacking inter­actions between the aromatic rings of the polycyclic ligands consolidate the sturcture [shortest centroid–centroid distance = 3.501 (2) Å]. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971279/ /pubmed/21578053 http://dx.doi.org/10.1107/S1600536809039154 Text en © Han et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Han, Qiang
Wang, Xiang-Cheng
Li, Xiu-Ying
Yao, Guan-Xin
Yan, Yong-Sheng
Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title_full Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title_fullStr Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title_full_unstemmed Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title_short Aqua­(2-hydr­oxy-5-sulfonatobenzoato-κO (1))bis­(2-phenyl-1H-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) N (7),N (8))zinc(II)
title_sort aqua­(2-hydr­oxy-5-sulfonatobenzoato-κo (1))bis­(2-phenyl-1h-1,3,7,8-tetra­aza­cyclo­penta­[l]phenanthrene-κ(2) n (7),n (8))zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971279/
https://www.ncbi.nlm.nih.gov/pubmed/21578053
http://dx.doi.org/10.1107/S1600536809039154
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