Tetra­aqua­bis[2-(thio­semi­carbazono­methyl)benzene­sulfonato]manganese(II)

In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry [Image: see text]) adopts a slightly distorted octa­hedral MnO(6) geometry. The mol­ecular conformation is supported by N—H⋯N and O—H⋯O hydrogen bonds. In the crystal, mol­ecules inter­act by O—H⋯O, O—H⋯S,...

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Detalles Bibliográficos
Autores principales: Tai, Xi-Shi, Zhao, Zeng-Bing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971282/
https://www.ncbi.nlm.nih.gov/pubmed/21578212
http://dx.doi.org/10.1107/S160053680904495X
Descripción
Sumario:In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry [Image: see text]) adopts a slightly distorted octa­hedral MnO(6) geometry. The mol­ecular conformation is supported by N—H⋯N and O—H⋯O hydrogen bonds. In the crystal, mol­ecules inter­act by O—H⋯O, O—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds, thereby forming (011) sheets.

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