Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)

The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino­methyl-5-methoxy­phenolate ligands...

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Detalles Bibliográficos
Autor principal: Tang, Chunbao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971283/
https://www.ncbi.nlm.nih.gov/pubmed/21578047
http://dx.doi.org/10.1107/S1600536809039233
Descripción
Sumario:The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino­methyl-5-methoxy­phenolate ligands. In the crystal, mol­ecules are linked into corrugated layers parallel to (100) by N—H⋯O hydrogen bonds.

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