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Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)

The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino­methyl-5-methoxy­phenolate ligands...

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Detalles Bibliográficos
Autor principal: Tang, Chunbao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971283/
https://www.ncbi.nlm.nih.gov/pubmed/21578047
http://dx.doi.org/10.1107/S1600536809039233
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author Tang, Chunbao
author_facet Tang, Chunbao
author_sort Tang, Chunbao
collection PubMed
description The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino­methyl-5-methoxy­phenolate ligands. In the crystal, mol­ecules are linked into corrugated layers parallel to (100) by N—H⋯O hydrogen bonds.
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spelling pubmed-29712832010-12-30 Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II) Tang, Chunbao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino­methyl-5-methoxy­phenolate ligands. In the crystal, mol­ecules are linked into corrugated layers parallel to (100) by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971283/ /pubmed/21578047 http://dx.doi.org/10.1107/S1600536809039233 Text en © Chunbao Tang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tang, Chunbao
Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title_full Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title_fullStr Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title_full_unstemmed Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title_short Bis(2-imino­methyl-5-methoxy­phenolato)nickel(II)
title_sort bis(2-imino­methyl-5-methoxy­phenolato)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971283/
https://www.ncbi.nlm.nih.gov/pubmed/21578047
http://dx.doi.org/10.1107/S1600536809039233
work_keys_str_mv AT tangchunbao bis2iminomethyl5methoxyphenolatonickelii