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Bis(2-iminomethyl-5-methoxyphenolato)nickel(II)
The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-iminomethyl-5-methoxyphenolate ligands...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971283/ https://www.ncbi.nlm.nih.gov/pubmed/21578047 http://dx.doi.org/10.1107/S1600536809039233 |
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author | Tang, Chunbao |
author_facet | Tang, Chunbao |
author_sort | Tang, Chunbao |
collection | PubMed |
description | The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-iminomethyl-5-methoxyphenolate ligands. In the crystal, molecules are linked into corrugated layers parallel to (100) by N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2971283 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712832010-12-30 Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) Tang, Chunbao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-iminomethyl-5-methoxyphenolate ligands. In the crystal, molecules are linked into corrugated layers parallel to (100) by N—H⋯O hydrogen bonds. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971283/ /pubmed/21578047 http://dx.doi.org/10.1107/S1600536809039233 Text en © Chunbao Tang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tang, Chunbao Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title | Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title_full | Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title_fullStr | Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title_full_unstemmed | Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title_short | Bis(2-iminomethyl-5-methoxyphenolato)nickel(II) |
title_sort | bis(2-iminomethyl-5-methoxyphenolato)nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971283/ https://www.ncbi.nlm.nih.gov/pubmed/21578047 http://dx.doi.org/10.1107/S1600536809039233 |
work_keys_str_mv | AT tangchunbao bis2iminomethyl5methoxyphenolatonickelii |