cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)

In the title compound, [Ag(3)(C(8)H(6)N(3))(3)], the asymmetric unit contains three silver cations and three depronated 5-(2-pyrid­yl)pyrazol-1-ide ligands. Each silver cation is chelated by one 5-(2-pyrid­yl)pyrazol-1-ide ligand, which also acts as a bridging ligand towards the next silver ion via...

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Detalles Bibliográficos
Autores principales: An, Zhe, Zhou, Ru-Jin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971284/
https://www.ncbi.nlm.nih.gov/pubmed/21578092
http://dx.doi.org/10.1107/S1600536809040082
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author An, Zhe
Zhou, Ru-Jin
author_facet An, Zhe
Zhou, Ru-Jin
author_sort An, Zhe
collection PubMed
description In the title compound, [Ag(3)(C(8)H(6)N(3))(3)], the asymmetric unit contains three silver cations and three depronated 5-(2-pyrid­yl)pyrazol-1-ide ligands. Each silver cation is chelated by one 5-(2-pyrid­yl)pyrazol-1-ide ligand, which also acts as a bridging ligand towards the next silver ion via the second pyrazole N atom. In summary, three silver cations and three deprotonated 3-(2-pyrid­yl)-1H-pyrazole ligands produce a macrocyclic trimeric coordination oligomer that exhibits an almost planar conformation (mean deviation 0.1483 Å). In addition, short non-bonding Ag⋯Ag inter­actions [3.127 (2) Å] are observed.
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spelling pubmed-29712842010-12-30 cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I) An, Zhe Zhou, Ru-Jin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(3)(C(8)H(6)N(3))(3)], the asymmetric unit contains three silver cations and three depronated 5-(2-pyrid­yl)pyrazol-1-ide ligands. Each silver cation is chelated by one 5-(2-pyrid­yl)pyrazol-1-ide ligand, which also acts as a bridging ligand towards the next silver ion via the second pyrazole N atom. In summary, three silver cations and three deprotonated 3-(2-pyrid­yl)-1H-pyrazole ligands produce a macrocyclic trimeric coordination oligomer that exhibits an almost planar conformation (mean deviation 0.1483 Å). In addition, short non-bonding Ag⋯Ag inter­actions [3.127 (2) Å] are observed. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971284/ /pubmed/21578092 http://dx.doi.org/10.1107/S1600536809040082 Text en © An and Zhou 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
An, Zhe
Zhou, Ru-Jin
cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title_full cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title_fullStr cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title_full_unstemmed cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title_short cyclo-Tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) N (1),N (5):N (2)]tris­ilver(I)
title_sort cyclo-tris[μ-5-(2-pyrid­yl)pyrazol-1-ido-κ(3) n (1),n (5):n (2)]tris­ilver(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971284/
https://www.ncbi.nlm.nih.gov/pubmed/21578092
http://dx.doi.org/10.1107/S1600536809040082
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AT zhourujin cyclotrism52pyridylpyrazol1idok3n1n5n2trisilveri

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