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3-Benzyl-7-methyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

In the title compound, C(32)H(32)N(2)O(2)S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a distorted half-chair conformation. The two rings are trans-fused. The dihedral angle between the sulfonyl and benzyl phenyl rings is 72.54 (14)°. The mol­ecular st...

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Detalles Bibliográficos
Autores principales: Chinnakali, K., Sudha, D., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971294/
https://www.ncbi.nlm.nih.gov/pubmed/21578502
http://dx.doi.org/10.1107/S1600536809044481
Descripción
Sumario:In the title compound, C(32)H(32)N(2)O(2)S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a distorted half-chair conformation. The two rings are trans-fused. The dihedral angle between the sulfonyl and benzyl phenyl rings is 72.54 (14)°. The mol­ecular structure is stabilized by C—H⋯O hydrogen bonds, and N—H⋯π inter­actions involving the benzyl phenyl ring. The screw-related mol­ecules are linked into chains along the b axis by C—H⋯O hydrogen bonds and C—H⋯π inter­actions. Adjacent inversion-related chains inter­act via C—H⋯π inter­actions, forming a two-dimensional network parallel to the bc plane.