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Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate
In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked toget...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/ https://www.ncbi.nlm.nih.gov/pubmed/21578055 http://dx.doi.org/10.1107/S1600536809039579 |
Sumario: | In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N interactions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion interacts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak intermolecular interactions contribute to the formation of supramolecular chains. In addition, there are Ag⋯O interactions [2.787 (2) Å] between Ag and O atoms from adjacent chains. |
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