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Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate

In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyano­benzyl­ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked toget...

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Detalles Bibliográficos
Autores principales: Niu, Cao-Yuan, Zhang, Hai-Yan, Wan, Xin-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/
https://www.ncbi.nlm.nih.gov/pubmed/21578055
http://dx.doi.org/10.1107/S1600536809039579
Descripción
Sumario:In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyano­benzyl­ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N inter­actions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion inter­acts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak inter­molecular inter­actions contribute to the formation of supra­molecular chains. In addition, there are Ag⋯O inter­actions [2.787 (2) Å] between Ag and O atoms from adjacent chains.