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Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate

In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyano­benzyl­ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked toget...

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Detalles Bibliográficos
Autores principales: Niu, Cao-Yuan, Zhang, Hai-Yan, Wan, Xin-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/
https://www.ncbi.nlm.nih.gov/pubmed/21578055
http://dx.doi.org/10.1107/S1600536809039579
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author Niu, Cao-Yuan
Zhang, Hai-Yan
Wan, Xin-Sheng
author_facet Niu, Cao-Yuan
Zhang, Hai-Yan
Wan, Xin-Sheng
author_sort Niu, Cao-Yuan
collection PubMed
description In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyano­benzyl­ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N inter­actions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion inter­acts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak inter­molecular inter­actions contribute to the formation of supra­molecular chains. In addition, there are Ag⋯O inter­actions [2.787 (2) Å] between Ag and O atoms from adjacent chains.
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spelling pubmed-29712962010-12-30 Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate Niu, Cao-Yuan Zhang, Hai-Yan Wan, Xin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyano­benzyl­ideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N inter­actions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion inter­acts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak inter­molecular inter­actions contribute to the formation of supra­molecular chains. In addition, there are Ag⋯O inter­actions [2.787 (2) Å] between Ag and O atoms from adjacent chains. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971296/ /pubmed/21578055 http://dx.doi.org/10.1107/S1600536809039579 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Niu, Cao-Yuan
Zhang, Hai-Yan
Wan, Xin-Sheng
Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title_full Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title_fullStr Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title_full_unstemmed Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title_short Bis[N′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κN]silver(I) trifluoro­methane­sulfonate
title_sort bis[n′-(3-cyano­benzyl­idene)isonicotino­hydrazide-κn]silver(i) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/
https://www.ncbi.nlm.nih.gov/pubmed/21578055
http://dx.doi.org/10.1107/S1600536809039579
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AT zhanghaiyan bisn3cyanobenzylideneisonicotinohydrazideknsilveritrifluoromethanesulfonate
AT wanxinsheng bisn3cyanobenzylideneisonicotinohydrazideknsilveritrifluoromethanesulfonate