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Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate
In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked toget...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/ https://www.ncbi.nlm.nih.gov/pubmed/21578055 http://dx.doi.org/10.1107/S1600536809039579 |
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author | Niu, Cao-Yuan Zhang, Hai-Yan Wan, Xin-Sheng |
author_facet | Niu, Cao-Yuan Zhang, Hai-Yan Wan, Xin-Sheng |
author_sort | Niu, Cao-Yuan |
collection | PubMed |
description | In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N interactions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion interacts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak intermolecular interactions contribute to the formation of supramolecular chains. In addition, there are Ag⋯O interactions [2.787 (2) Å] between Ag and O atoms from adjacent chains. |
format | Text |
id | pubmed-2971296 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29712962010-12-30 Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate Niu, Cao-Yuan Zhang, Hai-Yan Wan, Xin-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3), two N atoms from two independent pyridyl rings of two N′-3-cyanobenzylideneisonicotinohydrazide ligands coordinate to the unique Ag(I) ion, forming a nearly linear coordination geometry. Adjacent silver complexes are primarily linked together by Ag⋯N interactions, with Ag⋯N separations of 2.877 (2) and 3.314 (2) Å. On the other hand, one CF(3)SO(3) (−) anion interacts with hydrazone groups of two neighbouring ligands via N—H⋯O hydrogen bonds. These weak intermolecular interactions contribute to the formation of supramolecular chains. In addition, there are Ag⋯O interactions [2.787 (2) Å] between Ag and O atoms from adjacent chains. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971296/ /pubmed/21578055 http://dx.doi.org/10.1107/S1600536809039579 Text en © Niu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Niu, Cao-Yuan Zhang, Hai-Yan Wan, Xin-Sheng Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title_full | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title_fullStr | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title_full_unstemmed | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title_short | Bis[N′-(3-cyanobenzylidene)isonicotinohydrazide-κN]silver(I) trifluoromethanesulfonate |
title_sort | bis[n′-(3-cyanobenzylidene)isonicotinohydrazide-κn]silver(i) trifluoromethanesulfonate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971296/ https://www.ncbi.nlm.nih.gov/pubmed/21578055 http://dx.doi.org/10.1107/S1600536809039579 |
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