Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate

In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl­carbon­yl)pyridine-2-carboximidate (bpca) ligands and exhib­its a distorted octa­hedral coordination by six bpca N atoms. A classical O—H⋯O hydrogen bond exists between the...

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Detalles Bibliográficos
Autor principal: Wu, Dayu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971300/
https://www.ncbi.nlm.nih.gov/pubmed/21578096
http://dx.doi.org/10.1107/S1600536809040549
Descripción
Sumario:In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl­carbon­yl)pyridine-2-carboximidate (bpca) ligands and exhib­its a distorted octa­hedral coordination by six bpca N atoms. A classical O—H⋯O hydrogen bond exists between the methanol solvent mol­ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K.

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