Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate

In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl­carbon­yl)pyridine-2-carboximidate (bpca) ligands and exhib­its a distorted octa­hedral coordination by six bpca N atoms. A classical O—H⋯O hydrogen bond exists between the...

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Detalles Bibliográficos
Autor principal: Wu, Dayu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971300/
https://www.ncbi.nlm.nih.gov/pubmed/21578096
http://dx.doi.org/10.1107/S1600536809040549
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author Wu, Dayu
author_facet Wu, Dayu
author_sort Wu, Dayu
collection PubMed
description In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl­carbon­yl)pyridine-2-carboximidate (bpca) ligands and exhib­its a distorted octa­hedral coordination by six bpca N atoms. A classical O—H⋯O hydrogen bond exists between the methanol solvent mol­ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K.
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spelling pubmed-29713002010-12-30 Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate Wu, Dayu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Fe(C(12)H(8)N(3)O(2))(2)]ClO(4)·CH(3)OH, the iron(III) ion is surrounded by two tridentate N-(2-pyridyl­carbon­yl)pyridine-2-carboximidate (bpca) ligands and exhib­its a distorted octa­hedral coordination by six bpca N atoms. A classical O—H⋯O hydrogen bond exists between the methanol solvent mol­ecule and the perchlorate anion. Magnetic susceptibility measurements indicated the complex to be in the low-spin state in the temperature range 5–400 K. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971300/ /pubmed/21578096 http://dx.doi.org/10.1107/S1600536809040549 Text en © Dayu Wu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Dayu
Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_full Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_fullStr Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_full_unstemmed Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_short Bis[N-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(III) perchlorate methanol solvate
title_sort bis[n-(2-pyridylcarbon­yl)pyridine-2-carboximidato]iron(iii) perchlorate methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971300/
https://www.ncbi.nlm.nih.gov/pubmed/21578096
http://dx.doi.org/10.1107/S1600536809040549
work_keys_str_mv AT wudayu bisn2pyridylcarbonylpyridine2carboximidatoironiiiperchloratemethanolsolvate

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