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(5E)-5-(4-Hydroxy-3-methoxybenzylidene)-2-thioxo-1,3-thiazolidin-4-one methanol monosolvate
In the title compound, C(11)H(9)NO(3)S(2)·CH(4)O, the dihedral angle between the aromatic rings is 3.57 (16)° and intramolecular O—H⋯O and C—H⋯S interactions occur. In the crystal, the thiazolidin-4-one molecules are linked by N—H⋯O hydrogen bonds, forming chains. The hydrogen-bond motifs lead t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971307/ https://www.ncbi.nlm.nih.gov/pubmed/21578253 http://dx.doi.org/10.1107/S1600536809039567 |
Sumario: | In the title compound, C(11)H(9)NO(3)S(2)·CH(4)O, the dihedral angle between the aromatic rings is 3.57 (16)° and intramolecular O—H⋯O and C—H⋯S interactions occur. In the crystal, the thiazolidin-4-one molecules are linked by N—H⋯O hydrogen bonds, forming chains. The hydrogen-bond motifs lead to S(5), S(6) and R (3) (3)(8) ring motifs. There exist C=O⋯π interactions between the heterocyclic rings and π–π interactions between the heterocyclic and benzene rings at distances of 3.455 (2) and 3.602 (2) Å, respectively. The methanol solvent molecule is disordered over two sets of sites in a 0.542 (9):0.458 (9) ratio. |
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