(5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate

In the title compound, C(11)H(9)NO(3)S(2)·CH(4)O, the dihedral angle between the aromatic rings is 3.57 (16)° and intra­molecular O—H⋯O and C—H⋯S inter­actions occur. In the crystal, the thia­zolidin-4-one mol­ecules are linked by N—H⋯O hydrogen bonds, forming chains. The hydrogen-bond motifs lead t...

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Autores principales: Shahwar, Durre, Tahir, M. Nawaz, Raza, Muhammad Asam, Saddaf, Maria, Majeed, Sana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971307/
https://www.ncbi.nlm.nih.gov/pubmed/21578253
http://dx.doi.org/10.1107/S1600536809039567
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author Shahwar, Durre
Tahir, M. Nawaz
Raza, Muhammad Asam
Saddaf, Maria
Majeed, Sana
author_facet Shahwar, Durre
Tahir, M. Nawaz
Raza, Muhammad Asam
Saddaf, Maria
Majeed, Sana
author_sort Shahwar, Durre
collection PubMed
description In the title compound, C(11)H(9)NO(3)S(2)·CH(4)O, the dihedral angle between the aromatic rings is 3.57 (16)° and intra­molecular O—H⋯O and C—H⋯S inter­actions occur. In the crystal, the thia­zolidin-4-one mol­ecules are linked by N—H⋯O hydrogen bonds, forming chains. The hydrogen-bond motifs lead to S(5), S(6) and R (3) (3)(8) ring motifs. There exist C=O⋯π inter­actions between the heterocyclic rings and π–π inter­actions between the heterocyclic and benzene rings at distances of 3.455 (2) and 3.602 (2) Å, respectively. The methanol solvent mol­ecule is disordered over two sets of sites in a 0.542 (9):0.458 (9) ratio.
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spelling pubmed-29713072010-12-30 (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate Shahwar, Durre Tahir, M. Nawaz Raza, Muhammad Asam Saddaf, Maria Majeed, Sana Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(11)H(9)NO(3)S(2)·CH(4)O, the dihedral angle between the aromatic rings is 3.57 (16)° and intra­molecular O—H⋯O and C—H⋯S inter­actions occur. In the crystal, the thia­zolidin-4-one mol­ecules are linked by N—H⋯O hydrogen bonds, forming chains. The hydrogen-bond motifs lead to S(5), S(6) and R (3) (3)(8) ring motifs. There exist C=O⋯π inter­actions between the heterocyclic rings and π–π inter­actions between the heterocyclic and benzene rings at distances of 3.455 (2) and 3.602 (2) Å, respectively. The methanol solvent mol­ecule is disordered over two sets of sites in a 0.542 (9):0.458 (9) ratio. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971307/ /pubmed/21578253 http://dx.doi.org/10.1107/S1600536809039567 Text en © Shahwar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shahwar, Durre
Tahir, M. Nawaz
Raza, Muhammad Asam
Saddaf, Maria
Majeed, Sana
(5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title_full (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title_fullStr (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title_full_unstemmed (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title_short (5E)-5-(4-Hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
title_sort (5e)-5-(4-hydr­oxy-3-methoxy­benzyl­idene)-2-thioxo-1,3-thia­zolidin-4-one methanol monosolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971307/
https://www.ncbi.nlm.nih.gov/pubmed/21578253
http://dx.doi.org/10.1107/S1600536809039567
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