(E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol

In the mol­ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25 (8)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034 (13) Å] six-membered ring, which is oriented at dihedral angles of 0...

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Detalles Bibliográficos
Autores principales: Özek, Arzu, Albayrak, Çiğdem, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971308/
https://www.ncbi.nlm.nih.gov/pubmed/21578305
http://dx.doi.org/10.1107/S1600536809040586
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author Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
author_facet Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
author_sort Özek, Arzu
collection PubMed
description In the mol­ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25 (8)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034 (13) Å] six-membered ring, which is oriented at dihedral angles of 0.91 (1) and 28.91 (12)° with respect to the aromatic rings. The title mol­ecule is a phenol–imine tautomer, as evidenced by C—O, C—N and C—C bond lengths. In the crystal, mol­ecules are linked by inter­molecular C—H⋯O hydrogen bonds that generate C(8) chains.
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spelling pubmed-29713082010-12-30 (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol Özek, Arzu Albayrak, Çiğdem Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(16)H(17)NO(3), the aromatic rings are oriented at a dihedral angle of 29.25 (8)°. An intra­molecular O—H⋯N hydrogen bond results in the formation of a nearly planar [maximum deviation 0.034 (13) Å] six-membered ring, which is oriented at dihedral angles of 0.91 (1) and 28.91 (12)° with respect to the aromatic rings. The title mol­ecule is a phenol–imine tautomer, as evidenced by C—O, C—N and C—C bond lengths. In the crystal, mol­ecules are linked by inter­molecular C—H⋯O hydrogen bonds that generate C(8) chains. International Union of Crystallography 2009-10-10 /pmc/articles/PMC2971308/ /pubmed/21578305 http://dx.doi.org/10.1107/S1600536809040586 Text en © Özek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özek, Arzu
Albayrak, Çiğdem
Büyükgüngör, Orhan
(E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title_full (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title_fullStr (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title_full_unstemmed (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title_short (E)-2-[(4-Ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
title_sort (e)-2-[(4-ethoxy­phen­yl)imino­meth­yl]-4-methoxy­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971308/
https://www.ncbi.nlm.nih.gov/pubmed/21578305
http://dx.doi.org/10.1107/S1600536809040586
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