(η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate

The structure of the title compound, [Ru(C(10)H(15))(C(13)H(10)O)](C(24)H(20)B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetra­phenyl­borate anions (Cp* = penta­methyl­cyclo­penta­dien­yl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 ...

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Detalles Bibliográficos
Autores principales: Loughrey, Bradley T., Nadin, Kevin, Williams, Michael L., Healy, Peter C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971317/
https://www.ncbi.nlm.nih.gov/pubmed/21578208
http://dx.doi.org/10.1107/S1600536809042731
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author Loughrey, Bradley T.
Nadin, Kevin
Williams, Michael L.
Healy, Peter C.
author_facet Loughrey, Bradley T.
Nadin, Kevin
Williams, Michael L.
Healy, Peter C.
author_sort Loughrey, Bradley T.
collection PubMed
description The structure of the title compound, [Ru(C(10)H(15))(C(13)H(10)O)](C(24)H(20)B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetra­phenyl­borate anions (Cp* = penta­methyl­cyclo­penta­dien­yl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°.
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spelling pubmed-29713172010-12-30 (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate Loughrey, Bradley T. Nadin, Kevin Williams, Michael L. Healy, Peter C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Ru(C(10)H(15))(C(13)H(10)O)](C(24)H(20)B), consists of discrete [Cp*Ru(II)benzophenone] cations and tetra­phenyl­borate anions (Cp* = penta­methyl­cyclo­penta­dien­yl). Tethering the Cp*Ru group to one aryl ring of benzophenone results in average values of 1.42 (1) and 1.38 (1) Å for the C—C bond lengths in the Ru-tethered and untethered phenyl rings, respectively. The dihedral angle between the benzene and phenyl rings of the benzophenone group is 50.5 (1)°. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971317/ /pubmed/21578208 http://dx.doi.org/10.1107/S1600536809042731 Text en © Loughrey et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Loughrey, Bradley T.
Nadin, Kevin
Williams, Michael L.
Healy, Peter C.
(η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title_full (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title_fullStr (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title_full_unstemmed (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title_short (η(6)-Benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(II) tetra­phenyl­borate
title_sort (η(6)-benzophenone)(η(5)-penta­methyl­cyclo­penta­dien­yl)ruthenium(ii) tetra­phenyl­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971317/
https://www.ncbi.nlm.nih.gov/pubmed/21578208
http://dx.doi.org/10.1107/S1600536809042731
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AT williamsmichaell ē6benzophenoneē5pentamethylcyclopentadienylrutheniumiitetraphenylborate
AT healypeterc ē6benzophenoneē5pentamethylcyclopentadienylrutheniumiitetraphenylborate

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