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Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN (2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1)
In the title compound, [Cu(C(46)H(34)N(6))(CO)]PF(6)·0.75CH(2)Cl(2)·0.25C(4)H(10)O, the Cu(I) atom is coordinated by three N atoms from the tridentate chelating tris(3,5-diphenylpyrazol-1-yl)methane ligand (average Cu—N distance = 2.055 Å) and the C atom from a carbon monoxide ligand in a distorte...
Autores principales: | , , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971318/ https://www.ncbi.nlm.nih.gov/pubmed/21578109 http://dx.doi.org/10.1107/S1600536809040781 |
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author | Miller, Katie E. Schopp, Lauren M. Nesseth, Kelly N. Moore, Curtis Rheingold, Arnold L. Daley, Christopher J. A. |
author_facet | Miller, Katie E. Schopp, Lauren M. Nesseth, Kelly N. Moore, Curtis Rheingold, Arnold L. Daley, Christopher J. A. |
author_sort | Miller, Katie E. |
collection | PubMed |
description | In the title compound, [Cu(C(46)H(34)N(6))(CO)]PF(6)·0.75CH(2)Cl(2)·0.25C(4)H(10)O, the Cu(I) atom is coordinated by three N atoms from the tridentate chelating tris(3,5-diphenylpyrazol-1-yl)methane ligand (average Cu—N distance = 2.055 Å) and the C atom from a carbon monoxide ligand in a distorted tetrahedral coordination geometry. The average N—Cu—N angle between adjacent pyrazole-ring-coordinated N atoms is 88.6°, while the average N—Cu—C angle between the pyrazole-bound N atom and the C atom of carbon monoxide is 126.3°. One of the 3-phenyl rings of the tris(pyrazolyl)methane ligand is disordered over two sites each with an occupancy factor of 0.50. The structure also exhibits disorder of the monosolvate that has been modeled with 0.75 CH(2)Cl(2) and 0.25 Et(2)O occupancy. |
format | Text |
id | pubmed-2971318 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713182010-12-30 Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN (2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) Miller, Katie E. Schopp, Lauren M. Nesseth, Kelly N. Moore, Curtis Rheingold, Arnold L. Daley, Christopher J. A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(46)H(34)N(6))(CO)]PF(6)·0.75CH(2)Cl(2)·0.25C(4)H(10)O, the Cu(I) atom is coordinated by three N atoms from the tridentate chelating tris(3,5-diphenylpyrazol-1-yl)methane ligand (average Cu—N distance = 2.055 Å) and the C atom from a carbon monoxide ligand in a distorted tetrahedral coordination geometry. The average N—Cu—N angle between adjacent pyrazole-ring-coordinated N atoms is 88.6°, while the average N—Cu—C angle between the pyrazole-bound N atom and the C atom of carbon monoxide is 126.3°. One of the 3-phenyl rings of the tris(pyrazolyl)methane ligand is disordered over two sites each with an occupancy factor of 0.50. The structure also exhibits disorder of the monosolvate that has been modeled with 0.75 CH(2)Cl(2) and 0.25 Et(2)O occupancy. International Union of Crystallography 2009-10-13 /pmc/articles/PMC2971318/ /pubmed/21578109 http://dx.doi.org/10.1107/S1600536809040781 Text en © Miller et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Miller, Katie E. Schopp, Lauren M. Nesseth, Kelly N. Moore, Curtis Rheingold, Arnold L. Daley, Christopher J. A. Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN (2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title | Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN
(2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title_full | Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN
(2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title_fullStr | Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN
(2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title_full_unstemmed | Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN
(2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title_short | Carbonyl[tris(3,5-diphenylpyrazol-1-yl-κN
(2))methane]copper(I) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
title_sort | carbonyl[tris(3,5-diphenylpyrazol-1-yl-κn
(2))methane]copper(i) hexafluoridophosphate–dichloromethane–diethyl ether (4/3/1) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971318/ https://www.ncbi.nlm.nih.gov/pubmed/21578109 http://dx.doi.org/10.1107/S1600536809040781 |
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