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Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)

The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetra­hedrally around this atom. The benzene­thiol­ate ligand and...

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Detalles Bibliográficos
Autores principales: Monroe, Thomas Blake, Ikonen, Anita, Maner, Jonathon A., Jones, Daniel S., Striplin, Durwin R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971324/
https://www.ncbi.nlm.nih.gov/pubmed/21578157
http://dx.doi.org/10.1107/S1600536809041336
Descripción
Sumario:The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetra­hedrally around this atom. The benzene­thiol­ate ligand and the biquinoline ligand are nearly perpendicular to one another, making a dihedral angle of 84.09 (5)°. The biquinoline ligand is nearly planar, with a maximum deviation of 0.055 (3) Å from the mean plane of the ring system. In the crystal, the mol­ecules pack in a manner such that the biquinoline ligands are parallel to one another, with a π–π inter­action [interplanar distance = 3.38 (1) Å] with the neighboring biquinoline ligand.