Cargando…
Bis(benzenethiolato)(2,2′-biquinoline)zinc(II)
The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetrahedrally around this atom. The benzenethiolate ligand and...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971324/ https://www.ncbi.nlm.nih.gov/pubmed/21578157 http://dx.doi.org/10.1107/S1600536809041336 |
_version_ | 1782190600459649024 |
---|---|
author | Monroe, Thomas Blake Ikonen, Anita Maner, Jonathon A. Jones, Daniel S. Striplin, Durwin R. |
author_facet | Monroe, Thomas Blake Ikonen, Anita Maner, Jonathon A. Jones, Daniel S. Striplin, Durwin R. |
author_sort | Monroe, Thomas Blake |
collection | PubMed |
description | The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetrahedrally around this atom. The benzenethiolate ligand and the biquinoline ligand are nearly perpendicular to one another, making a dihedral angle of 84.09 (5)°. The biquinoline ligand is nearly planar, with a maximum deviation of 0.055 (3) Å from the mean plane of the ring system. In the crystal, the molecules pack in a manner such that the biquinoline ligands are parallel to one another, with a π–π interaction [interplanar distance = 3.38 (1) Å] with the neighboring biquinoline ligand. |
format | Text |
id | pubmed-2971324 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713242010-12-30 Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) Monroe, Thomas Blake Ikonen, Anita Maner, Jonathon A. Jones, Daniel S. Striplin, Durwin R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetrahedrally around this atom. The benzenethiolate ligand and the biquinoline ligand are nearly perpendicular to one another, making a dihedral angle of 84.09 (5)°. The biquinoline ligand is nearly planar, with a maximum deviation of 0.055 (3) Å from the mean plane of the ring system. In the crystal, the molecules pack in a manner such that the biquinoline ligands are parallel to one another, with a π–π interaction [interplanar distance = 3.38 (1) Å] with the neighboring biquinoline ligand. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971324/ /pubmed/21578157 http://dx.doi.org/10.1107/S1600536809041336 Text en © Monroe et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Monroe, Thomas Blake Ikonen, Anita Maner, Jonathon A. Jones, Daniel S. Striplin, Durwin R. Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title | Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title_full | Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title_fullStr | Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title_full_unstemmed | Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title_short | Bis(benzenethiolato)(2,2′-biquinoline)zinc(II) |
title_sort | bis(benzenethiolato)(2,2′-biquinoline)zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971324/ https://www.ncbi.nlm.nih.gov/pubmed/21578157 http://dx.doi.org/10.1107/S1600536809041336 |
work_keys_str_mv | AT monroethomasblake bisbenzenethiolato22biquinolinezincii AT ikonenanita bisbenzenethiolato22biquinolinezincii AT manerjonathona bisbenzenethiolato22biquinolinezincii AT jonesdaniels bisbenzenethiolato22biquinolinezincii AT striplindurwinr bisbenzenethiolato22biquinolinezincii |