Cargando…

Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)

The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetra­hedrally around this atom. The benzene­thiol­ate ligand and...

Descripción completa

Detalles Bibliográficos
Autores principales: Monroe, Thomas Blake, Ikonen, Anita, Maner, Jonathon A., Jones, Daniel S., Striplin, Durwin R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971324/
https://www.ncbi.nlm.nih.gov/pubmed/21578157
http://dx.doi.org/10.1107/S1600536809041336
_version_ 1782190600459649024
author Monroe, Thomas Blake
Ikonen, Anita
Maner, Jonathon A.
Jones, Daniel S.
Striplin, Durwin R.
author_facet Monroe, Thomas Blake
Ikonen, Anita
Maner, Jonathon A.
Jones, Daniel S.
Striplin, Durwin R.
author_sort Monroe, Thomas Blake
collection PubMed
description The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetra­hedrally around this atom. The benzene­thiol­ate ligand and the biquinoline ligand are nearly perpendicular to one another, making a dihedral angle of 84.09 (5)°. The biquinoline ligand is nearly planar, with a maximum deviation of 0.055 (3) Å from the mean plane of the ring system. In the crystal, the mol­ecules pack in a manner such that the biquinoline ligands are parallel to one another, with a π–π inter­action [interplanar distance = 3.38 (1) Å] with the neighboring biquinoline ligand.
format Text
id pubmed-2971324
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29713242010-12-30 Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II) Monroe, Thomas Blake Ikonen, Anita Maner, Jonathon A. Jones, Daniel S. Striplin, Durwin R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(6)H(5)S)(2)(C(18)H(12)N(2))], was prepared as a model for future complexes that will be incorporated into light-harvesting arrays. The Zn(II) atom lies on a twofold rotation axis and the ligands are arranged tetra­hedrally around this atom. The benzene­thiol­ate ligand and the biquinoline ligand are nearly perpendicular to one another, making a dihedral angle of 84.09 (5)°. The biquinoline ligand is nearly planar, with a maximum deviation of 0.055 (3) Å from the mean plane of the ring system. In the crystal, the mol­ecules pack in a manner such that the biquinoline ligands are parallel to one another, with a π–π inter­action [interplanar distance = 3.38 (1) Å] with the neighboring biquinoline ligand. International Union of Crystallography 2009-10-23 /pmc/articles/PMC2971324/ /pubmed/21578157 http://dx.doi.org/10.1107/S1600536809041336 Text en © Monroe et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Monroe, Thomas Blake
Ikonen, Anita
Maner, Jonathon A.
Jones, Daniel S.
Striplin, Durwin R.
Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title_full Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title_fullStr Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title_full_unstemmed Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title_short Bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(II)
title_sort bis­(benzene­thiol­ato)(2,2′-biquinoline)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971324/
https://www.ncbi.nlm.nih.gov/pubmed/21578157
http://dx.doi.org/10.1107/S1600536809041336
work_keys_str_mv AT monroethomasblake bisbenzenethiolato22biquinolinezincii
AT ikonenanita bisbenzenethiolato22biquinolinezincii
AT manerjonathona bisbenzenethiolato22biquinolinezincii
AT jonesdaniels bisbenzenethiolato22biquinolinezincii
AT striplindurwinr bisbenzenethiolato22biquinolinezincii