Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)

In the crystal structure of the title compound, [Cu(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(H(2)O)], the Cu(II) ion is penta­coordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and a...

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Detalles Bibliográficos
Autores principales: Dong, Xi-Yan, Xu, Xiaojie, Yang, Lei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971325/
https://www.ncbi.nlm.nih.gov/pubmed/21578058
http://dx.doi.org/10.1107/S1600536809039191
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author Dong, Xi-Yan
Xu, Xiaojie
Yang, Lei
author_facet Dong, Xi-Yan
Xu, Xiaojie
Yang, Lei
author_sort Dong, Xi-Yan
collection PubMed
description In the crystal structure of the title compound, [Cu(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(H(2)O)], the Cu(II) ion is penta­coordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. The crystal studied was a racemic twin, as suggested by the Flack parameter of 0.584 (14).
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spelling pubmed-29713252010-12-30 Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II) Dong, Xi-Yan Xu, Xiaojie Yang, Lei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Cu(C(7)H(5)O(2))(2)(C(12)H(12)N(2))(H(2)O)], the Cu(II) ion is penta­coordinated in a distorted square-pyramidal geometry by two O atoms of two benzoate anions and two N atoms of a 5,5′-dimethyl-2,2′-bipyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. The crystal studied was a racemic twin, as suggested by the Flack parameter of 0.584 (14). International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971325/ /pubmed/21578058 http://dx.doi.org/10.1107/S1600536809039191 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Xi-Yan
Xu, Xiaojie
Yang, Lei
Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title_full Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title_fullStr Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title_short Aqua­bis(benzoato-κO)(5,5′-dimethyl-2,2′-bipyridine-κ(2) N,N′)copper(II)
title_sort aqua­bis(benzoato-κo)(5,5′-dimethyl-2,2′-bipyridine-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971325/
https://www.ncbi.nlm.nih.gov/pubmed/21578058
http://dx.doi.org/10.1107/S1600536809039191
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AT xuxiaojie aquabisbenzoatoko55dimethyl22bipyridinek2nncopperii
AT yanglei aquabisbenzoatoko55dimethyl22bipyridinek2nncopperii

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