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3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline

In the title compound, C(31)H(30)N(2)O(2)S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The pyridine-bound phenyl ring forms dihedral angles of 17.7 (1) and 48.1 (1)°, respectively, with the tosy...

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Detalles Bibliográficos
Autores principales: Chinnakali, K., Sudha, D., Jayagobi, M., Raghunathan, R., Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971326/
https://www.ncbi.nlm.nih.gov/pubmed/21578501
http://dx.doi.org/10.1107/S1600536809044547
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author Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_facet Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
author_sort Chinnakali, K.
collection PubMed
description In the title compound, C(31)H(30)N(2)O(2)S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The pyridine-bound phenyl ring forms dihedral angles of 17.7 (1) and 48.1 (1)°, respectively, with the tosyl and benzyl phenyl rings. The mol­ecular structure is stabilized by an N—H⋯π inter­action involving the benzyl phenyl ring. In the crystal structure, mol­ecules translated by one unit along the a axis are linked into chains by C—H⋯π inter­actions involving the benzene ring of the tosyl group.
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spelling pubmed-29713262010-12-30 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline Chinnakali, K. Sudha, D. Jayagobi, M. Raghunathan, R. Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(30)N(2)O(2)S, the pyrrolidine ring adopts a twist conformation while the tetra­hydro­pyridine ring is in a half-chair conformation. The two rings are trans-fused. The pyridine-bound phenyl ring forms dihedral angles of 17.7 (1) and 48.1 (1)°, respectively, with the tosyl and benzyl phenyl rings. The mol­ecular structure is stabilized by an N—H⋯π inter­action involving the benzyl phenyl ring. In the crystal structure, mol­ecules translated by one unit along the a axis are linked into chains by C—H⋯π inter­actions involving the benzene ring of the tosyl group. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971326/ /pubmed/21578501 http://dx.doi.org/10.1107/S1600536809044547 Text en © Chinnakali et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chinnakali, K.
Sudha, D.
Jayagobi, M.
Raghunathan, R.
Fun, Hoong-Kun
3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title_full 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title_fullStr 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title_full_unstemmed 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title_short 3-Benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1H-pyrrolo[3,4-b]quinoline
title_sort 3-benzyl-9-phenyl-2-tosyl-2,3,3a,4,9,9a-hexa­hydro-1h-pyrrolo[3,4-b]quinoline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971326/
https://www.ncbi.nlm.nih.gov/pubmed/21578501
http://dx.doi.org/10.1107/S1600536809044547
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