Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)

The mol­ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of...

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Detalles Bibliográficos
Autores principales: Dong, Lei, Yin, Handong, Wen, Liyuan, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971330/
https://www.ncbi.nlm.nih.gov/pubmed/21578170
http://dx.doi.org/10.1107/S1600536809043542
Descripción
Sumario:The mol­ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy­benzaldehyde oximate ligands. An intra­molecular O—H⋯N inter­action is present. The crystal structure is stabilized by C—H⋯O inter­actions.

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