Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)

The mol­ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of...

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Detalles Bibliográficos
Autores principales: Dong, Lei, Yin, Handong, Wen, Liyuan, Wang, Daqi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971330/
https://www.ncbi.nlm.nih.gov/pubmed/21578170
http://dx.doi.org/10.1107/S1600536809043542
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author Dong, Lei
Yin, Handong
Wen, Liyuan
Wang, Daqi
author_facet Dong, Lei
Yin, Handong
Wen, Liyuan
Wang, Daqi
author_sort Dong, Lei
collection PubMed
description The mol­ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy­benzaldehyde oximate ligands. An intra­molecular O—H⋯N inter­action is present. The crystal structure is stabilized by C—H⋯O inter­actions.
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spelling pubmed-29713302010-12-30 Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V) Dong, Lei Yin, Handong Wen, Liyuan Wang, Daqi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecule of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], is located on a twofold axis defined by the metal center and two C atoms of a coordinated phenyl group. The Sb center has a slightly distorted trigonal-bipyramidal geometry, with the axial positions occupied by the O atoms of symmetry-related 2-hydroxy­benzaldehyde oximate ligands. An intra­molecular O—H⋯N inter­action is present. The crystal structure is stabilized by C—H⋯O inter­actions. International Union of Crystallography 2009-10-28 /pmc/articles/PMC2971330/ /pubmed/21578170 http://dx.doi.org/10.1107/S1600536809043542 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dong, Lei
Yin, Handong
Wen, Liyuan
Wang, Daqi
Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title_full Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title_fullStr Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title_full_unstemmed Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title_short Bis(2-hydroxy­benzaldehyde oximato-κO)triphenyl­anti­mony(V)
title_sort bis(2-hydroxy­benzaldehyde oximato-κo)triphenyl­anti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971330/
https://www.ncbi.nlm.nih.gov/pubmed/21578170
http://dx.doi.org/10.1107/S1600536809043542
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AT yinhandong bis2hydroxybenzaldehydeoximatokotriphenylantimonyv
AT wenliyuan bis2hydroxybenzaldehydeoximatokotriphenylantimonyv
AT wangdaqi bis2hydroxybenzaldehydeoximatokotriphenylantimonyv

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