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4,4′-Bipyridinium bis(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971331/ https://www.ncbi.nlm.nih.gov/pubmed/21578048 http://dx.doi.org/10.1107/S1600536809039117 |
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author | Zhang, Lai-Jun Shen, Xing-Can Liang, Hong |
author_facet | Zhang, Lai-Jun Shen, Xing-Can Liang, Hong |
author_sort | Zhang, Lai-Jun |
collection | PubMed |
description | The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre is coordinated by four O atoms from the two dicrete oxalate ligands [Cu—O = 1.9245 (19) and 1.9252 (17) Å], while the planar dications are also centrosymmetric. Inter-species N—H⋯O hydrogen bonds link the cations and anions into one-dimensional chains and, together with weak intra-ion C—H⋯O interactions, give a two-dimensional sheet structure. |
format | Text |
id | pubmed-2971331 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29713312010-12-30 4,4′-Bipyridinium bis(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex Zhang, Lai-Jun Shen, Xing-Can Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre is coordinated by four O atoms from the two dicrete oxalate ligands [Cu—O = 1.9245 (19) and 1.9252 (17) Å], while the planar dications are also centrosymmetric. Inter-species N—H⋯O hydrogen bonds link the cations and anions into one-dimensional chains and, together with weak intra-ion C—H⋯O interactions, give a two-dimensional sheet structure. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971331/ /pubmed/21578048 http://dx.doi.org/10.1107/S1600536809039117 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Lai-Jun Shen, Xing-Can Liang, Hong 4,4′-Bipyridinium bis(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex |
title | 4,4′-Bipyridinium bis(oxalato-κ(2)
O
(1),O
(2))cuprate(II): an ion-pair complex |
title_full | 4,4′-Bipyridinium bis(oxalato-κ(2)
O
(1),O
(2))cuprate(II): an ion-pair complex |
title_fullStr | 4,4′-Bipyridinium bis(oxalato-κ(2)
O
(1),O
(2))cuprate(II): an ion-pair complex |
title_full_unstemmed | 4,4′-Bipyridinium bis(oxalato-κ(2)
O
(1),O
(2))cuprate(II): an ion-pair complex |
title_short | 4,4′-Bipyridinium bis(oxalato-κ(2)
O
(1),O
(2))cuprate(II): an ion-pair complex |
title_sort | 4,4′-bipyridinium bis(oxalato-κ(2)
o
(1),o
(2))cuprate(ii): an ion-pair complex |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971331/ https://www.ncbi.nlm.nih.gov/pubmed/21578048 http://dx.doi.org/10.1107/S1600536809039117 |
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