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4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex

The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre...

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Detalles Bibliográficos
Autores principales: Zhang, Lai-Jun, Shen, Xing-Can, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971331/
https://www.ncbi.nlm.nih.gov/pubmed/21578048
http://dx.doi.org/10.1107/S1600536809039117
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author Zhang, Lai-Jun
Shen, Xing-Can
Liang, Hong
author_facet Zhang, Lai-Jun
Shen, Xing-Can
Liang, Hong
author_sort Zhang, Lai-Jun
collection PubMed
description The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre is coordinated by four O atoms from the two dicrete oxalate ligands [Cu—O = 1.9245 (19) and 1.9252 (17) Å], while the planar dications are also centrosymmetric. Inter-species N—H⋯O hydrogen bonds link the cations and anions into one-dimensional chains and, together with weak intra-ion C—H⋯O inter­actions, give a two-dimensional sheet structure.
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spelling pubmed-29713312010-12-30 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex Zhang, Lai-Jun Shen, Xing-Can Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(10)H(10)N(2))[Cu(C(2)O(4))(2)] or (4,4′-H(2)bpy)[Cu(ox)(2)] (bpy is 4,4′-bipyridine and ox is oxalate), is an ion-pair complex comprising a protonated 4,4′-bipyridinium dication and a square-planar dioxalatocopper(II) dianion. In the centrosymmetric dianion, the Cu(II) centre is coordinated by four O atoms from the two dicrete oxalate ligands [Cu—O = 1.9245 (19) and 1.9252 (17) Å], while the planar dications are also centrosymmetric. Inter-species N—H⋯O hydrogen bonds link the cations and anions into one-dimensional chains and, together with weak intra-ion C—H⋯O inter­actions, give a two-dimensional sheet structure. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971331/ /pubmed/21578048 http://dx.doi.org/10.1107/S1600536809039117 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhang, Lai-Jun
Shen, Xing-Can
Liang, Hong
4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title_full 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title_fullStr 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title_full_unstemmed 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title_short 4,4′-Bipyridinium bis­(oxalato-κ(2) O (1),O (2))cuprate(II): an ion-pair complex
title_sort 4,4′-bipyridinium bis­(oxalato-κ(2) o (1),o (2))cuprate(ii): an ion-pair complex
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971331/
https://www.ncbi.nlm.nih.gov/pubmed/21578048
http://dx.doi.org/10.1107/S1600536809039117
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