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Poly[[aqua(μ-4,4′-bipyridine-κ(2) N:N′)(μ(3)-2-nitro-5-sulfonatobenzoato-κ(3) O (1):O (1′):O (5))copper(II)] 4,4′-bipyridine hemisolvate]
In the title compound, [Cu(C(7)H(3)NO(7)S)(C(10)H(8)N(2))(H(2)O)]·0.5C(10)H(8)N(2), the Cu(II) atom is six-coordinated by two N atoms from two different bipyridine (bipy) ligands, one sulfonate O atom and two carboxylate O atoms from three 2-nitro-5-sulfonatobenzoate ligands and one water O atom in...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971335/ https://www.ncbi.nlm.nih.gov/pubmed/21578045 http://dx.doi.org/10.1107/S1600536809039294 |
Sumario: | In the title compound, [Cu(C(7)H(3)NO(7)S)(C(10)H(8)N(2))(H(2)O)]·0.5C(10)H(8)N(2), the Cu(II) atom is six-coordinated by two N atoms from two different bipyridine (bipy) ligands, one sulfonate O atom and two carboxylate O atoms from three 2-nitro-5-sulfonatobenzoate ligands and one water O atom in a distorted octahedral geometry. The bipy solvent molecule lies on an inversion center. The Cu(II) atoms are linked by the bipy ligands, forming one-dimensional chains, which are connected by the 2-nitro-5-sulfonatobenzoate ligands into a two-dimensional layer-like network. The two-dimensional structure is extended by O—H⋯O and O—H⋯N hydrogen bonds into a three-dimensional supramolecular network. |
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