2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one

In the title compound, C(15)H(9)BrCl(2)O, the two benzene rings are twisted from each other with a dihedral angle of 47.33 (8)°. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.680 (2) Å], and by w...

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Detalles Bibliográficos
Autores principales: Harrison, William T. A., Hakim Al-Arique, Q. N. M., Narayana, B., Yathirajan, H. S., Sarojini, B. K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971337/
https://www.ncbi.nlm.nih.gov/pubmed/21578262
http://dx.doi.org/10.1107/S160053680903815X
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author Harrison, William T. A.
Hakim Al-Arique, Q. N. M.
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
author_facet Harrison, William T. A.
Hakim Al-Arique, Q. N. M.
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
author_sort Harrison, William T. A.
collection PubMed
description In the title compound, C(15)H(9)BrCl(2)O, the two benzene rings are twisted from each other with a dihedral angle of 47.33 (8)°. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.680 (2) Å], and by weak inter­molecular C—H⋯O and C—H⋯Cl inter­actions. Additionally, the crystal structure exhibits a short intra­molecular C—H⋯Br contact (H⋯Br = 2.69 Å).
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spelling pubmed-29713372010-12-30 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one Harrison, William T. A. Hakim Al-Arique, Q. N. M. Narayana, B. Yathirajan, H. S. Sarojini, B. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(9)BrCl(2)O, the two benzene rings are twisted from each other with a dihedral angle of 47.33 (8)°. The crystal structure is stabilized by aromatic π–π inter­actions between the benzene rings of neighbouring mol­ecules [centroid–centroid distance = 3.680 (2) Å], and by weak inter­molecular C—H⋯O and C—H⋯Cl inter­actions. Additionally, the crystal structure exhibits a short intra­molecular C—H⋯Br contact (H⋯Br = 2.69 Å). International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971337/ /pubmed/21578262 http://dx.doi.org/10.1107/S160053680903815X Text en © Harrison et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Harrison, William T. A.
Hakim Al-Arique, Q. N. M.
Narayana, B.
Yathirajan, H. S.
Sarojini, B. K.
2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title_full 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title_fullStr 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title_full_unstemmed 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title_short 2-Bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
title_sort 2-bromo-1,3-bis­(4-chloro­phen­yl)prop-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971337/
https://www.ncbi.nlm.nih.gov/pubmed/21578262
http://dx.doi.org/10.1107/S160053680903815X
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AT yathirajanhs 2bromo13bis4chlorophenylprop2en1one
AT sarojinibk 2bromo13bis4chlorophenylprop2en1one

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