(η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate

The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru—P = 2.3585 (4) and 2.3312 (4) Å, and Ru—N = 2.0422 (15) Å as the legs...

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Detalles Bibliográficos
Autores principales: Mauthner, Klaus, Kirchner, Karl, Mereiter, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971339/
https://www.ncbi.nlm.nih.gov/pubmed/21578041
http://dx.doi.org/10.1107/S1600536809038720
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author Mauthner, Klaus
Kirchner, Karl
Mereiter, Kurt
author_facet Mauthner, Klaus
Kirchner, Karl
Mereiter, Kurt
author_sort Mauthner, Klaus
collection PubMed
description The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru—P = 2.3585 (4) and 2.3312 (4) Å, and Ru—N = 2.0422 (15) Å as the legs. The CF(3)SO(3) (−) anion is anchored in the crystal lattice by C—H⋯O and C—H⋯F hydrogen bonds, with C⋯F,O distances starting at 3.125 (2) Å.
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spelling pubmed-29713392010-12-30 (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate Mauthner, Klaus Kirchner, Karl Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru—P = 2.3585 (4) and 2.3312 (4) Å, and Ru—N = 2.0422 (15) Å as the legs. The CF(3)SO(3) (−) anion is anchored in the crystal lattice by C—H⋯O and C—H⋯F hydrogen bonds, with C⋯F,O distances starting at 3.125 (2) Å. International Union of Crystallography 2009-10-03 /pmc/articles/PMC2971339/ /pubmed/21578041 http://dx.doi.org/10.1107/S1600536809038720 Text en © Mauthner et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mauthner, Klaus
Kirchner, Karl
Mereiter, Kurt
(η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title_full (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title_fullStr (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title_full_unstemmed (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title_short (η(5)-Cyclo­penta­dien­yl)(propionitrile-κN)bis­(triphenyl­phosphine-κP)ruthenium(II) trifluoro­methane­sulfonate
title_sort (η(5)-cyclo­penta­dien­yl)(propionitrile-κn)bis­(triphenyl­phosphine-κp)ruthenium(ii) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971339/
https://www.ncbi.nlm.nih.gov/pubmed/21578041
http://dx.doi.org/10.1107/S1600536809038720
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AT mereiterkurt ē5cyclopentadienylpropionitrileknbistriphenylphosphinekprutheniumiitrifluoromethanesulfonate

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