Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate

The binuclear title compound, [Hf(2)(C(5)HF(6)O(2))(6)(OH)(2)]·C(3)H(6)O, contains an Hf(IV) atom which is eight coordinated and surrounded by three chelating β-diketonato 1,1,1,5,5,5-hexa­fluoro­acetyl­acetonate (hfaa) ligands and two bridging OH groups situated on a twofold rotation axis. The HfO(...

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Autores principales: Viljoen, J. Augustinus, Visser, Hendrik G., Roodt, Andreas, Steyn, Maryke
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971352/
https://www.ncbi.nlm.nih.gov/pubmed/21578120
http://dx.doi.org/10.1107/S1600536809041658
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author Viljoen, J. Augustinus
Visser, Hendrik G.
Roodt, Andreas
Steyn, Maryke
author_facet Viljoen, J. Augustinus
Visser, Hendrik G.
Roodt, Andreas
Steyn, Maryke
author_sort Viljoen, J. Augustinus
collection PubMed
description The binuclear title compound, [Hf(2)(C(5)HF(6)O(2))(6)(OH)(2)]·C(3)H(6)O, contains an Hf(IV) atom which is eight coordinated and surrounded by three chelating β-diketonato 1,1,1,5,5,5-hexa­fluoro­acetyl­acetonate (hfaa) ligands and two bridging OH groups situated on a twofold rotation axis. The HfO(8) coordination polyhedron shows a slightly distorted Archimedean square anti-prismatic coordination with average Hf—O, C—O, C—C(Me) distances of 2.19 (2), 1.26 (2) and 1.49 (2) Å, respectively, and an O—Hf—O bite angle of 75.3 (5)°. Weak O—H⋯O hydrogen bonding inter­actions are observed between one of the bridging hydr­oxy groups and the disordered solvent mol­ecule.
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spelling pubmed-29713522010-12-30 Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate Viljoen, J. Augustinus Visser, Hendrik G. Roodt, Andreas Steyn, Maryke Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The binuclear title compound, [Hf(2)(C(5)HF(6)O(2))(6)(OH)(2)]·C(3)H(6)O, contains an Hf(IV) atom which is eight coordinated and surrounded by three chelating β-diketonato 1,1,1,5,5,5-hexa­fluoro­acetyl­acetonate (hfaa) ligands and two bridging OH groups situated on a twofold rotation axis. The HfO(8) coordination polyhedron shows a slightly distorted Archimedean square anti-prismatic coordination with average Hf—O, C—O, C—C(Me) distances of 2.19 (2), 1.26 (2) and 1.49 (2) Å, respectively, and an O—Hf—O bite angle of 75.3 (5)°. Weak O—H⋯O hydrogen bonding inter­actions are observed between one of the bridging hydr­oxy groups and the disordered solvent mol­ecule. International Union of Crystallography 2009-10-17 /pmc/articles/PMC2971352/ /pubmed/21578120 http://dx.doi.org/10.1107/S1600536809041658 Text en © Viljoen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Viljoen, J. Augustinus
Visser, Hendrik G.
Roodt, Andreas
Steyn, Maryke
Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title_full Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title_fullStr Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title_full_unstemmed Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title_short Di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) O,O′)hafnium(IV)] acetone solvate
title_sort di-μ-hydroxido-bis[tris(1,1,1,5,5,5-hexa­fluoro­acetyl­acetonato-κ(2) o,o′)hafnium(iv)] acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971352/
https://www.ncbi.nlm.nih.gov/pubmed/21578120
http://dx.doi.org/10.1107/S1600536809041658
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AT roodtandreas dimhydroxidobistris111555hexafluoroacetylacetonatok2oohafniumivacetonesolvate
AT steynmaryke dimhydroxidobistris111555hexafluoroacetylacetonatok2oohafniumivacetonesolvate

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