(5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one

The mol­ecular framework of the title compound, C(11)H(7)IOS(8), is almost planar [maximum deviation = 0.040 (4) Å], except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, making C—S—C—C torsion angles of 144.1 (8) and −141.3 (8)°. In the crystal, mol­ecule...

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Detalles Bibliográficos
Autores principales: Ueda, Kazumasa, Yoza, Kenji
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971353/
https://www.ncbi.nlm.nih.gov/pubmed/21578498
http://dx.doi.org/10.1107/S1600536809044493
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author Ueda, Kazumasa
Yoza, Kenji
author_facet Ueda, Kazumasa
Yoza, Kenji
author_sort Ueda, Kazumasa
collection PubMed
description The mol­ecular framework of the title compound, C(11)H(7)IOS(8), is almost planar [maximum deviation = 0.040 (4) Å], except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, making C—S—C—C torsion angles of 144.1 (8) and −141.3 (8)°. In the crystal, mol­ecules are stacked alternately in opposite orientations, forming a one-dimensional column parallel to [110]. The primary inter­actions between mol­ecules comprising the columns are of the S⋯S type [3.554 (1) Å]. Inter­actions between columns are of the S⋯S type [3.411 (1) along b and 3.444 (1) Å along c], as well as S⋯I contacts [3.435 (2) Å].
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spelling pubmed-29713532010-12-30 (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one Ueda, Kazumasa Yoza, Kenji Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular framework of the title compound, C(11)H(7)IOS(8), is almost planar [maximum deviation = 0.040 (4) Å], except for the two methyl­sulfanyl groups, which are twisted relative to the mol­ecular skeleton, making C—S—C—C torsion angles of 144.1 (8) and −141.3 (8)°. In the crystal, mol­ecules are stacked alternately in opposite orientations, forming a one-dimensional column parallel to [110]. The primary inter­actions between mol­ecules comprising the columns are of the S⋯S type [3.554 (1) Å]. Inter­actions between columns are of the S⋯S type [3.411 (1) along b and 3.444 (1) Å along c], as well as S⋯I contacts [3.435 (2) Å]. International Union of Crystallography 2009-10-31 /pmc/articles/PMC2971353/ /pubmed/21578498 http://dx.doi.org/10.1107/S1600536809044493 Text en © Ueda and Yoza 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ueda, Kazumasa
Yoza, Kenji
(5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title_full (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title_fullStr (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title_full_unstemmed (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title_short (5E)-2-[4,5-Bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
title_sort (5e)-2-[4,5-bis(methyl­sulfan­yl)-1,3-dithiol-2-yl­idene]-5-(4-iodo-1,3-dithiol-2-yl­idene)-1,3-dithio­lan-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971353/
https://www.ncbi.nlm.nih.gov/pubmed/21578498
http://dx.doi.org/10.1107/S1600536809044493
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AT yozakenji 5e245bismethylsulfanyl13dithiol2ylidene54iodo13dithiol2ylidene13dithiolan4one

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