Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]

The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano­late anions. Each Al atom is tetra­coordinated by two bridging O atoms from two different 9-anthracenemethano­late ligands and by two C atoms from two methyl groups, forming a dist...

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Detalles Bibliográficos
Autores principales: Li, Chen-Yu, Lin, Chia-Her, Liu, Yi-Chang, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971356/
https://www.ncbi.nlm.nih.gov/pubmed/21578083
http://dx.doi.org/10.1107/S1600536809040161
Descripción
Sumario:The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano­late anions. Each Al atom is tetra­coordinated by two bridging O atoms from two different 9-anthracenemethano­late ligands and by two C atoms from two methyl groups, forming a distorted tetra­hedral environment. The average Al—O bond distance in the Al(2)O(2) core is 1.845 Å.

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