Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]

The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano­late anions. Each Al atom is tetra­coordinated by two bridging O atoms from two different 9-anthracenemethano­late ligands and by two C atoms from two methyl groups, forming a dist...

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Detalles Bibliográficos
Autores principales: Li, Chen-Yu, Lin, Chia-Her, Liu, Yi-Chang, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971356/
https://www.ncbi.nlm.nih.gov/pubmed/21578083
http://dx.doi.org/10.1107/S1600536809040161
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author Li, Chen-Yu
Lin, Chia-Her
Liu, Yi-Chang
Ko, Bao-Tsan
author_facet Li, Chen-Yu
Lin, Chia-Her
Liu, Yi-Chang
Ko, Bao-Tsan
author_sort Li, Chen-Yu
collection PubMed
description The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano­late anions. Each Al atom is tetra­coordinated by two bridging O atoms from two different 9-anthracenemethano­late ligands and by two C atoms from two methyl groups, forming a distorted tetra­hedral environment. The average Al—O bond distance in the Al(2)O(2) core is 1.845 Å.
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spelling pubmed-29713562010-12-30 Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)] Li, Chen-Yu Lin, Chia-Her Liu, Yi-Chang Ko, Bao-Tsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano­late anions. Each Al atom is tetra­coordinated by two bridging O atoms from two different 9-anthracenemethano­late ligands and by two C atoms from two methyl groups, forming a distorted tetra­hedral environment. The average Al—O bond distance in the Al(2)O(2) core is 1.845 Å. International Union of Crystallography 2009-10-07 /pmc/articles/PMC2971356/ /pubmed/21578083 http://dx.doi.org/10.1107/S1600536809040161 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chen-Yu
Lin, Chia-Her
Liu, Yi-Chang
Ko, Bao-Tsan
Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title_full Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title_fullStr Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title_full_unstemmed Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title_short Bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(III)]
title_sort bis(μ-9-anthracenemethano­lato)bis­[dimethyl­aluminium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2971356/
https://www.ncbi.nlm.nih.gov/pubmed/21578083
http://dx.doi.org/10.1107/S1600536809040161
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